TY - JOUR AU1 - Ol’khov, Yu. AU2 - Allayarov, S. AU3 - Allayarova, U. AU4 - Dixon, D. AB - The molecular–topological structure of a terpolymer based on vinylidene fluoride, hexafluoropropylene, and tetrafluoroethylene has been studied for the first time with the use of thermomechanical spectrometry. A five-block topologically amorphous and crystalline pseudo-network structure with crystallites, which have different initial melting temperatures, as branching points has been detected in the terpolymer at temperatures from–100 to 250°C. When γ-irradiated at a dose of 30 kGy, the crystalline blocks of high-temperature modifications assimilated into one cluster block with the formation of a pseudo-network with a 1.5fold increase in the block-average molecular weight and a decreased initial molecular flow temperature. TI - Effect of γ-irradiation on the molecular-topological structure of Viton® fluoroelastomers JF - High Energy Chemistry DO - 10.1134/S0018143916010045 DA - 2016-03-30 UR - https://www.deepdyve.com/lp/springer-journals/effect-of-irradiation-on-the-molecular-topological-structure-of-viton-M0a19kFr6B SP - 101 EP - 108 VL - 50 IS - 2 DP - DeepDyve ER -