TY - JOUR
AU - Fu, Yao
AB - A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate. 92% yield of the acetates was obtained through the tandem benzoin condensation and hydrodeoxygenation reaction. During the benzoin condensation, furfural was catalyzed into furoin in a quantitative yield by the immobilized NHC catalyst under solvent-free conditions. After dissolving the furoin intermediate in acetic acid, the Sc(OTf)3 and Pd/C catalytic system was introduced for hydrodeoxygenation. The effects of reaction factors have been investigated in detail and the hydrodeoxygenation process has been explored by 1H-NMR and GC-MS.
TI - Synthesis of 1,10-decanediol diacetate and 1-decanol acetate from furfural
JF - Green Chemistry
DO - 10.1039/d1gc00227a
DA - 2021-03-15
UR - https://www.deepdyve.com/lp/royal-society-of-chemistry/synthesis-of-1-10-decanediol-diacetate-and-1-decanol-acetate-from-LyBfTKP0b0
SP - 2169
EP - 2176
VL - 23
IS - 5
DP - DeepDyve
ER -