TY - JOUR
AU1 - Abrahams, Brendan F.
AU2 - Commons, Christopher J.
AU3 - Hudson, Timothy A.
AU4 - Sanchez Arlt, Robin
AU5 - Ahl, Rion
AU6 - Carajias, Eirene D.
AU7 - Chan, Jason W. K.
AU8 - Guo, Zhihao
AU9 - Hill, Renee E.
AU1 - McGinty, Alice
AU1 - Peters, Neale L.
AU1 - Poon, Joshua Y. P.
AU1 - Qu, Jingqi
AU1 - Qu, Jinglin
AU1 - Rochette, Emily E.
AU1 - Walkear, Catherine
AU1 - Wang, Hanlin
AU1 - Wu, Holly
AU1 - Xu, Chang
AU2 - Zhang, Jingyuan
AB - This article describes a series of more than 20 new compounds formed by the combination of 2,4,6‐trihydroxybenzoic acid (H4thba) with metal ions in the presence of a base, with structures that include discrete molecular units, chains, and two‐ and three‐dimensional networks. As a result of the presence of two ortho‐hydroxy groups, H4thba is a relatively strong acid (pKa1 = 1.68). The carboxylate group in H3thba− is therefore considerably less basic than most carboxylates with intramolecular hydrogen bonds, conferring a rigid planar geometry upon the anion. These characteristics of H3thba− significantly impact upon the way it interacts with metal ions. In s‐block metal compounds, where the interaction of the metal centres with the carboxylate O atoms is essentially ionic, the anion bonds to up to three metal centres via a variety of binding modes. In cases where the metal ion is able to form directional coordinate bonds, however, the carboxylate group tends to bond in a monodentate mode, interacting with just one metal centre in the syn mode. A dominant influence on the structures of the complexes seems to be the face‐to‐face stacking of the aromatic rings, which creates networks containing layers of metal–oxygen polyhedra that participate in hydrogen bonding. This investigation was undertaken, in part, by a group of secondary school students as an educational exercise designed to introduce school students to the technique of single‐crystal X‐ray diffraction and enhance their understanding of primary and secondary bonding.
TI - Complexes of 2,4,6‐trihydroxybenzoic acid: effects of intramolecular hydrogen bonding on ligand geometry and metal binding modes
JF - Acta Crystallographica Section C Crystal Structure Communications
DO - 10.1107/s2053229622009901
DA - 2022-11-01
UR - https://www.deepdyve.com/lp/wiley/complexes-of-2-4-6-trihydroxybenzoic-acid-effects-of-intramolecular-LAPLCeGvgP
SP - 653
EP - 670
VL - 78
IS - 11
DP - DeepDyve
ER -