TY - JOUR
AU - Oka, Shinzaburo
AB - Reduction of 1-phenyl-2-(2-pyridyl)-1,2-ethanedione with 1-benzyl-1,4-dihydronicotinamide in acetonitrile in the presence of zinc perchlorate has been studied. The α-diketone coordinates onto zinc ion through its pyridine-ring nitrogen and benzene-side carbonyl oxygen, whereas the reduction takes place on pyridine-side carbonyl group. It is concluded that an effective ligand to a metal ion is not necessarily a facile substrate of the reduction.
TI - Reduction by a Model of NAD(P)H. 28. Reduction of an α-Diketone in the Presence of Zinc Ion
JF - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.53.3244
DA - 2006-04-19
UR - https://www.deepdyve.com/lp/oxford-university-press/reduction-by-a-model-of-nad-p-h-28-reduction-of-an-diketone-in-the-L1FwV5Lqw6
SP - 3244
EP - 3247
VL - 53
IS - 11
DP - DeepDyve
ER -