TY - JOUR
AU1 - Li, Ting‐Ting
AU2 - Kuang, Xiaofei
AU3 - Wang, Ming‐Ming
AU4 - Yang, Hui
AU5 - Mi, Ying‐Hao
AU6 - Lu, Can‐Zhong
AB - Photoactive Cu(I) complexes are promising luminescent materials owing to their abundant reserves and marvelous biocompatibility. In this work, we report the synthesis and characterization of two binuclear sulfur‐bridged Cu(I) complexes (POP)2Cu2(μ‐HS/Cl)2 ⋅ 0.92MeOH 1 (POP=(oxybis(2,1‐phenylene))bis(diphenylphosphine)) and (POP)2Cu2(μ‐HS)2 2, which were prepared by one‐pot facile solvothermal method with copper‐4‐tert‐butylbenzenethiol (CuSC6H4tBu) and POP as precursors. Complex 1 exhibits sky‐blue emission while complex 2 displays blue. Complex 1 was systemically investigated by PXRD, UV‐vis spectrum, IR, TGA and steady‐state spectra. Temperature‐dependent steady‐state emission and decay lifetime indicate that complex 1 is a typical phosphorescent emitter.
TI - Synthesis and Characterization of Luminescent Binuclear μ‐HS Cu(I) Complexes
JF - Zeitschrift für anorganische und allgemeine Chemie
DO - 10.1002/zaac.202300032
DA - 2023-06-01
UR - https://www.deepdyve.com/lp/wiley/synthesis-and-characterization-of-luminescent-binuclear-hs-cu-i-Gsw0Irkofd
VL - 649
IS - 11-12
DP - DeepDyve
ER -