TY - JOUR
AU - Fukin, Georgy K.
AB - The reaction of (dpp-BIAN)Mg(THF)3 (1) with anhydrous CrCl3 in THF at 80 °C affords the mixed chromium–magnesium complex (dpp-BIAN)Cr(μ-Cl)3Mg(THF)3 (2). The treatment of 2 with 1,4-dioxane causes the elimination of MgCl2 and the formation of dimeric [(dpp-BIAN)Cr(μ-Cl)(THF)]2 (3). The reaction of (dpp-BIAN)Na2 with CrCl3 gives the chlorine-free compound [Na(THF)6][(dpp-BIAN)2Cr] (4). Paramagnetic complexes 2, 3 and 4 have been characterized by IR and electronic absorption spectroscopy. The magnetic susceptibilities of 2 and 4 have been determined in solution using Evans’ method. The molecular structures of 2–4 have been established by single crystal X-ray analysis.
TI - Acenaphthene-1,2-diimine chromium complexes
JF - Dalton Transactions
DO - 10.1039/b909814c
DA - 2009-09-22
UR - https://www.deepdyve.com/lp/royal-society-of-chemistry/acenaphthene-1-2-diimine-chromium-complexes-8mc2nH7I0s
SP - 8047
EP - 8053
VL - 
IS - 38
DP - DeepDyve
ER -