TY - JOUR AU - Nancollas, G.H. AB - The kinetics of dissolution of powdered bovine enamel and of human enamel, both untreated and extracted with either hypochlorite or chloroform, has been studied using a constant solution composition technique in undersaturated solutions of calcium phosphate (total molar calcium concentration, TCa = 0.3 to 13.1 × 10-3 mol L-1, total molar phosphate, Tp = 0.18 to 7.9 x 10-3 mol L-1) at an ionic strength of 0.15 mol L-1, and pH = 4.5. The kinetic equations describing the dissolution reactions suggest a surface dislocation mechanism, and the presence of fluoride ion markedly retarded the reaction. For human enamel, a fluoride level of only 0.5 ppm reduced the rate of dissolution ten-fold. In contrast, the dissolution of hydroxyapatite, HAP, is best interpreted in terms of a polynucleation process. TI - The Kinetics of Dissolution of Tooth Enamel — A Constant Composition Study JF - Journal of Dental Research DO - 10.1177/00220345860650050601 DA - 1986-05-01 UR - https://www.deepdyve.com/lp/sage/the-kinetics-of-dissolution-of-tooth-enamel-a-constant-composition-8NRd8nAjdw SP - 663 EP - 668 VL - 65 IS - 5 DP - DeepDyve ER -