TY - JOUR
AU - Shida, Shoji
AB - Carbon dioxide and sulfur hexafluoride have been used as electron scavengers in the γ-radiolysis of cyclohexane. The dependence of G(H2) on the concentrations of additives can be interpreted satisfactorily in terms of diffusion-controlled reactions between electrons and the additives. A simple calculation was made using a function proportional to r2exp(−αr2) for the initial distribution of secondary electrons. The distribution constant α and the value of G(electrons) were adjusted to make the calculated curve of G(H2) vs- scanvenger concentration coincide with the observed one. The average initial separation of the secondary electron from the parent positive ion was found to be about 50 Å, and G(electrons) = 3.
TI - Secondary Electrons in the Radiolysis of Cyclohexane
JO - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.40.1818
DA - 2006-03-27
UR - https://www.deepdyve.com/lp/oxford-university-press/secondary-electrons-in-the-radiolysis-of-cyclohexane-8HfjFATZTQ
SP - 1818
EP - 1822
VL - 40
IS - 8
DP - DeepDyve
ER -