TY - JOUR
AU - Yamamoto, Hisashi
AB - Silyl superpowers: The supersilyl group was investigated as a superior carboxylic acid protecting group. Supersilyl esters were also utilized as stable carboxylic acid synthetic equivalents in highly stereoselective aldol and Mannich reactions (see scheme). The value of this method lies in easy photodeprotection and in the rapid synthesis of polyketide subunits.
TI - The Supersilyl Group as a Carboxylic Acid Protecting Group: Application to Highly Stereoselective Aldol and Mannich Reactions
JF - Angewandte Chemie International Edition
DO - 10.1002/anie.201300102
DA - 2013-08-08
UR - https://www.deepdyve.com/lp/wiley/the-supersilyl-group-as-a-carboxylic-acid-protecting-group-application-84hRr6fUEh
SP - 7198
EP - 7202
VL - 52
IS - 28
DP - DeepDyve
ER -