TY - JOUR
AU - Kato, Shunji
AB - UV spectra of [Ni(2,2′-bipyridyl)3]Cl2 and [Ni(2,2′-bipyridyl)(H2O)4]Cl2 in the mixed solvent of methanol and water (4:1) were measured at 4.2 K. No difference between the spectra indicates a small splitting (<90 cm−1) between the exciton states extending through the three 2,2′-bipyridyls. Since the UV spectrum of [Ni(1,10-phenanthroline)3]Cl2 has a band with the progression as that of [Ni(1,10-phenanthroline)(H2O)4]SO4, a molecular exciton interaction between the three 1,10-phenanthrolines is not strong.
TI - Ligand-Ligand Interaction in Tris(2,2′-bipyridyl) and Tris (1,10-phenanthroline) Complexes of Nickel(II)
JF - Bulletin of the Chemical Society of Japan
DO - 10.1246/bcsj.48.2014
DA - 2006-03-27
UR - https://www.deepdyve.com/lp/oxford-university-press/ligand-ligand-interaction-in-tris-2-2-bipyridyl-and-tris-1-10-5Ap6DImYMS
SP - 2014
EP - 2016
VL - 48
IS - 7
DP - DeepDyve
ER -