TY - JOUR AU - Medina-Torres, L AB - The effect of natural rubber (NR) on mechanical, chemical and thermal properties of ground tire rubber (GTR) was investigated. Mechanical and thermal properties of GTR/NR vulcanized blends were determined with a universal testing machine and a dynamic mechanical analyzer (DMA). The molecular cross-linking density was determined by molecular swelling in toluene. Presents results indicate that the carbon black embedded in the GTR interior phase of the GTR/NR re-vulcanized blends, did not participate in the NR phase molecular motion restriction. The blends of GTR/NR showed the phenomenon known as reversion, leading a decreasing of the mechanical properties, that could be attributed of the degradation of the interphases (GTR/NR) n+j, j=1,2,3,…. On the other hand, the Cole-Cole charts of the GTR/NR vulcanized blends changed from a semicircular to an irregular form as the NR concentration increases, imposing the heterogeneity of the blend. In addition, in the Cole-Cole charts of GTR/NR vulcanized and re-vulcanized blends, the height (E´´) and the width (E´) of the curves decreased while the re-vulcanization processes number was greater; obtained results could be attributed to the increasing of the molecular cross-linking density. TI - Mechanical properties, dynamic mechanical analysis and molecular cross-linking of GTR/NR re-Vulcanized blends JF - "Progress in Rubber, Plastics and Recycling" DO - 10.1177/14777606221127370 DA - 2022-11-01 UR - https://www.deepdyve.com/lp/sage/mechanical-properties-dynamic-mechanical-analysis-and-molecular-cross-3jdvCjsIwX SP - 280 EP - 294 VL - 38 IS - 4 DP - DeepDyve ER -