TY - JOUR
AU - Zhao, Jun
AB - Presented here are two d10 metal–organic coordination polymers (CPs), [Zn(C4O4)0.5(μ
3-OH)]
n
 (1) and [Cd(C4O4)0.5(OX)0.5(H2O)]
n
 (2) (H2OX = oxalic acid) constructed from squaric acid (H2C4O4) tectons. Single-crystal X-ray diffraction studies indicated that both 1 and 2 show 3D structures. The two 3D CPs are assembled from 1D {[Zn(μ
3-OH)]

n

+
} chains to 3D structure linked through C4O4
2− ligands for 1 and 2D {[(Cd1)2(C4O4)]2+} layers pillared by OX2− ligands for 2. The structure of compound 1 can be described as a trinodal (3,6,6)-connected net with the point symbol of {43}2{44·610·8}{45·610}2, whereas 2 possess a trinodal (4,5,6)-connected {42·84} {46·66·83} {48·62}2 topology. Furthermore, the fluorescent and thermal stabilities properties of these two compounds were investigated.
TI - Two New Zn(II)/Cd(II) Coordination Polymers Based on Rigid Squaric Acid: Crystal Structure, Topology and Fluorescent Properties
JF - Journal of Inorganic and Organometallic Polymers and Materials
DO - 10.1007/s10904-014-0118-9
DA - 2014-11-11
UR - https://www.deepdyve.com/lp/springer-journals/two-new-zn-ii-cd-ii-coordination-polymers-based-on-rigid-squaric-acid-2FOUP9riF3
SP - 569
EP - 575
VL - 25
IS - 3
DP - DeepDyve
ER -