TY - JOUR
AU - RunZhang, Yuan
AB - A method for preparing a self-humidifying composite membrane for the polymer electrolyte membrane fuel cells (PEMFCs) is presented. In this method, perfluorosulfonylfluroride resin is impregnated into a PTFE porous support and positively charged poly(diallymethylammonium)-Pt nanoparticles are self-assembled into the composite membrane to form a self-humidifying layer. The self-assembled Pt nanoparticles were dispersed uniformly in the composite membrane and serve as the catalytic center for the combination reaction between the crossover hydrogen and oxygen, effectively self-humidifying the membrane. The self-assembly of Pt nanoparticles has little adverse effect on the proton conductivity of the composite membrane. The composite membrane with self-assembled Pt nanoparticles improves significantly the performance of PEMFCs as compared to that of the composite membrane without self-assembled Pt nanoparticles. The results show that optimum loading of the self-assembled Pt nanoparticle is about  under conditions of the present study.
TI - A Self-Humidifying Composite Membrane with Self-Assembled Pt Nanoparticles for Polymer Electrolyte Membrane Fuel Cells
JF - Journal of the Electrochemical Society
DO - 10.1149/1.2234730
DA - 2006-08-04
UR - https://www.deepdyve.com/lp/iop-publishing/a-self-humidifying-composite-membrane-with-self-assembled-pt-1Dthfc0Z0u
SP - A1868
EP - A1872
VL - 153
IS - 10
DP - DeepDyve
ER -