TY - JOUR
AU - Aruga, Roberto
AB - Summary The enthalpies of the first step of complex formation of 1-methylimidazole with CoII, NiII, CuII and ZnII have been determined by direct calorimetry. By means of the equilibrium constants, the Gibbs functions and entropies were also obtained. The measurements were carried out in aqueous medium, at 25 °C and an ionic strength I=1 mol dm−3 (NaNO3). The present results and the previous thermodynamic data for associations of pyrazole and imidazole are used to infer the quality of the metal-ligand bonds and particularly their π-character.
TI - Thermodynamics of complex formation of 1-methylimidazole with cobalt(II), nickel(II), copper(II) and zinc(II) cations in aqueous solution
JF - Transition Metal Chemistry
DO - 10.1007/bf00618801
DA - 1983-02-01
UR - https://www.deepdyve.com/lp/springer-journals/thermodynamics-of-complex-formation-of-1-methylimidazole-with-cobalt-0WR1JuU5Op
SP - 56
EP - 58
VL - 8
IS - 1
DP - DeepDyve
ER -