TY - JOUR AU1 - Oh, Changhoon AU2 - Kang, Minwook AU3 - Hahn, Jae Won AB - Abstract We measure the density of atomic chlorine radicals in inductive coupled plasma (ICP) with an optical emission spectrometer (OES). Our results revealed a transition point in the dissociation rate of molecular chlorine with respect to radio frequency (RF) power; above the transition point, the signal interference in the measurement of atomic chlorine radical density by dissociated molecular chlorine becomes negligibly small. Based on the dissociation rate of the molecular chlorine, we determine appropriate conditions for accurate measurement of atomic chlorine radical density with an uncertainty of less than 2.4%. By applying argon-based optical actinometry, we measure the distribution of atomic chlorine radical density on a 12-inch wafer to predict the chrome ICP etch process used to fabricate lithographic photomasks in the semiconductor industry. We also find that the distribution of atomic chlorine radical density is in good agreement with the etch rate of the chrome thin film. TI - Accurate measurement of atomic chlorine radical density in process plasma with spatially resolvable optical emission spectrometer JF - "International Journal of Precision Engineering and Manufacturing" DO - 10.1007/s12541-015-0249-0 DA - 2015-08-01 UR - https://www.deepdyve.com/lp/springer-journals/accurate-measurement-of-atomic-chlorine-radical-density-in-process-01OqbO0UQx SP - 1919 EP - 1924 VL - 16 IS - 9 DP - DeepDyve ER -