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Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat

Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit... <jats:p>Reactions of chloro bridged complexes with R-3-(3-pyridyl)alanine afford the chelate complexes L<jats:sub>n</jats:sub>M[NH<jats:sub>2</jats:sub>CH(CO<jats:sub>2</jats:sub>)CH<jats:sub>2</jats:sub>C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sup>+</jats:sup>]Cl<jats:sup>−</jats:sup> (L<jats:sub>n</jats:sub>M = Ph<jats:sub>3</jats:sub>P(Cl)Pd, (tol<jats:sub>3</jats:sub>P)(Cl)Pd, (Ph-pyridyl)<jats:sub>2</jats:sub>Ir, Cp٭(Cl)Rh, Cp٭(Cl)Ir, (p-Cymol)(Cl)Ru) with protonated pyridine substituents. An analogous Cp٭Rh complex with 3-(2-pyridyl)alaninate was also obtained. Addition of base (NaOMe) to these complexes gives dimeric and trimeric complexes with coordination of the pyridine N atom.</jats:p> http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Zeitschrift für Naturforschung B CrossRef

Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat

Zeitschrift für Naturforschung B , Volume 58 (4): 318-323 – Apr 1, 2003

Metallkomplexe mit biologisch wichtigen Liganden, CLI [1]. Metallorganische Komplexe mit R-3-(3-Pyridyl)alaninat


Abstract

<jats:p>Reactions of chloro bridged complexes with R-3-(3-pyridyl)alanine afford the chelate complexes L<jats:sub>n</jats:sub>M[NH<jats:sub>2</jats:sub>CH(CO<jats:sub>2</jats:sub>)CH<jats:sub>2</jats:sub>C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sup>+</jats:sup>]Cl<jats:sup>−</jats:sup> (L<jats:sub>n</jats:sub>M = Ph<jats:sub>3</jats:sub>P(Cl)Pd, (tol<jats:sub>3</jats:sub>P)(Cl)Pd, (Ph-pyridyl)<jats:sub>2</jats:sub>Ir, Cp٭(Cl)Rh, Cp٭(Cl)Ir, (p-Cymol)(Cl)Ru) with protonated pyridine substituents. An analogous Cp٭Rh complex with 3-(2-pyridyl)alaninate was also obtained. Addition of base (NaOMe) to these complexes gives dimeric and trimeric complexes with coordination of the pyridine N atom.</jats:p>

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Publisher
CrossRef
ISSN
1865-7117
DOI
10.1515/znb-2003-0411
Publisher site
See Article on Publisher Site

Abstract

<jats:p>Reactions of chloro bridged complexes with R-3-(3-pyridyl)alanine afford the chelate complexes L<jats:sub>n</jats:sub>M[NH<jats:sub>2</jats:sub>CH(CO<jats:sub>2</jats:sub>)CH<jats:sub>2</jats:sub>C<jats:sub>5</jats:sub>H<jats:sub>4</jats:sub>NH<jats:sup>+</jats:sup>]Cl<jats:sup>−</jats:sup> (L<jats:sub>n</jats:sub>M = Ph<jats:sub>3</jats:sub>P(Cl)Pd, (tol<jats:sub>3</jats:sub>P)(Cl)Pd, (Ph-pyridyl)<jats:sub>2</jats:sub>Ir, Cp٭(Cl)Rh, Cp٭(Cl)Ir, (p-Cymol)(Cl)Ru) with protonated pyridine substituents. An analogous Cp٭Rh complex with 3-(2-pyridyl)alaninate was also obtained. Addition of base (NaOMe) to these complexes gives dimeric and trimeric complexes with coordination of the pyridine N atom.</jats:p>

Journal

Zeitschrift für Naturforschung BCrossRef

Published: Apr 1, 2003

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