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- Publisher
- CSIRO Publishing
- Copyright
- Copyright © The Author(s). Published by CSIRO Publishing
- ISSN
- 0004-9425
- eISSN
- 1445-0038
- DOI
- 10.1071/CH15826
- Publisher site
- See Article on Publisher Site
Abstract
A new chromogenic receptor, 4-((2,4-dichlorophenyl)diazenyl)-2-(3-hydroxypropylimino)methyl)phenol, has been designed and synthesized for quantitative and low-cost detection of various biological anions and cations. The dye was characterized by elemental analyses, infrared, UV-visible spectroscopy, and NMR spectroscopy. The chemosensor showed visual changes towards anions, such as F and H2PO4, in DMSO and towards cations, such as Al3, Cu2, Fe3, and Cr3, in DMSO/water (9:1). The anion recognition property of the receptor via proton transfer was monitored by UV-visible titration and 1H NMR spectroscopy. The binding constant (Ka) and stoichiometry of the hostguest complexes formed were determined by the BenesiHildebrand (BH) plot and Job's method, respectively.
Journal
Australian Journal of Chemistry – CSIRO Publishing
Published: Apr 4, 2016