Microwave-Assisted Synthesis of Vinyl Esters through Ruthenium-Catalyzed Addition of Carboxylic Acids to Alkynes
Microwave-Assisted Synthesis of Vinyl Esters through Ruthenium-Catalyzed Addition of Carboxylic...
Nicks François F.; Libert Lionel L.; Delaude Lionel L.; Demonceau Albert A.
2009-03-20 00:00:00
A rapid and efficient method is described for the selective synthesis of enol esters via the microwave-accelerated addition of carboxylic acids to terminal alkynes. The method employs the readily available (RuCl 2 ( p -cymene)(PPh 3 )) complex as catalyst without the need of bases, and reactions are complete in 20 min.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngAustralian Journal of ChemistryCSIRO Publishinghttp://www.deepdyve.com/lp/csiro-publishing/microwave-assisted-synthesis-of-vinyl-esters-through-ruthenium-0MvozeG9Sk
Microwave-Assisted Synthesis of Vinyl Esters through Ruthenium-Catalyzed Addition of Carboxylic Acids to Alkynes
A rapid and efficient method is described for the selective synthesis of enol esters via the microwave-accelerated addition of carboxylic acids to terminal alkynes. The method employs the readily available (RuCl 2 ( p -cymene)(PPh 3 )) complex as catalyst without the need of bases, and reactions are complete in 20 min.
Journal
Australian Journal of Chemistry
– CSIRO Publishing
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