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Huayan Yang, Yu Wang, Xi Chen, Xiaojing Zhao, Lin Gu, Huaqi Huang, Juanzhu Yan, Chaofa Xu, Gang Li, Junchao Wu, A. Edwards, B. Dittrich, Zi-Chao Tang, Dong-dong Wang, L. Lehtovaara, H. Häkkinen, N. Zheng (2016)
Plasmonic twinned silver nanoparticles with molecular precisionNature Communications, 7
S. Kenzler, Claudio Schrenk, A. Schnepf (2017)
Au108 S24 (PPh3 )16 : A Highly Symmetric Nanoscale Gold Cluster Confirms the General Concept of Metalloid Clusters.Angewandte Chemie, 56 1
S. Xie, H. Tsunoyama, Wataru Kurashige, Y. Negishi, T. Tsukuda (2012)
Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom DopingACS Catalysis, 2
Tatsuya Higaki, Meng Zhou, Kelly Lambright, K. Kirschbaum, M. Sfeir, Rongchao Jin (2018)
Sharp Transition from Nonmetallic Au246 to Metallic Au279 with Nascent Surface Plasmon Resonance.Journal of the American Chemical Society, 140 17
Hannu Häkkinen, Stéphane Abbet, A. Sánchez, U. Heiz, Uzi Landman (2003)
Einfluss der geometrischen und elektronischen Struktur sowie der elementaren Zusammensetzung von Clustern auf chemische Prozesse in der NanometerskalaAngewandte Chemie, 115
Zhen Lei, Jiao-Jiao Li, Xian-Kai Wan, Wen-Han Zhang, Quan‐Ming Wang (2018)
Isolation and Total Structure Determination of an All-Alkynyl-Protected Gold Nanocluster Au144.Angewandte Chemie, 57 28
N. Sakthivel, Shevanuja Theivendran, Vigneshraja Ganeshraj, A. Oliver, A. Dass (2017)
Crystal Structure of Faradaurate-279: Au279(SPh-tBu)84 Plasmonic Nanocrystal Molecules.Journal of the American Chemical Society, 139 43
Yu Wang, Xian-Kai Wan, Liting Ren, Haifeng Su, Gang Li, Sami Malola, Shui-Lian Lin, Zi-Chao Tang, H. Häkkinen, B. Teo, Quan‐Ming Wang, N. Zheng (2016)
Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles.Journal of the American Chemical Society, 138 10
S. Link, M. El-Sayed (2003)
Optical properties and ultrafast dynamics of metallic nanocrystals.Annual review of physical chemistry, 54
K. Mayer, Jana Weßing, T. Fässler, R. Fischer (2018)
Intermetalloid Clusters: Molecules and Solids in a Dialogue.Angewandte Chemie, 57 44
Yongbo Song, Kelly Lambright, Meng Zhou, K. Kirschbaum, J. Xiang, A. Xia, Manzhou Zhu, Rongchao Jin (2018)
Large-Scale Synthesis, Crystal Structure, and Optical Properties of the Ag146Br2(SR)80 Nanocluster.ACS nano, 12 9
A. Tlahuice‐Flores (2015)
New insight into the structure of thiolated gold clusters: a structural prediction of the Au187(SR)68 cluster.Physical chemistry chemical physics : PCCP, 17 8
K. Chakrahari, R. Silalahi, Tzu-Hao Chiu, Xiaoping Wang, Nadia Azrou, S. Kahlal, Yu-Chiao Liu, M. Chiang, J. Saillard, Chen-Wei Liu (2019)
Synthesis of Bimetallic Copper-Rich Nanoclusters Encapsulating a Linear Palladium Dihydride Unit.Angewandte Chemie, 58 15
Jiu-Lian Zeng, Zong‐Jie Guan, Yang Du, Zi‐Ang Nan, Yu-Mei Lin, Quan‐Ming Wang (2016)
Chloride-Promoted Formation of a Bimetallic Nanocluster Au80Ag30 and the Total Structure Determination.Journal of the American Chemical Society, 138 25
Tiankai Chen, Qiaofeng Yao, R. Nasaruddin, Jianping Xie (2019)
Electrospray Ionization Mass Spectrometry: A Powerful Platform for Noble‐Metal Nanocluster AnalysisAngewandte Chemie
Sandra Vergara, Dylan Lukes, M. Martynowycz, U. Santiago, G. Plascencia‐Villa, S. Weiss, M. Cruz, D. Black, M. Alvarez, X. López-Lozano, C. Barnes, Guowu Lin, Hans-Christian Weissker, R. Whetten, T. Gonen, Guillermo Antonio, U. Pittsburgh, Howard Institute, A. Universit'e, U. Angeles (2017)
MicroED Structure of Au146(p-MBA)57 at Subatomic Resolution Reveals a Twinned FCC Cluster.The journal of physical chemistry letters, 8 22
Zibao Gan, Nan Xia, Zhikun Wu (2018)
Discovery, Mechanism, and Application of Antigalvanic Reaction.Accounts of chemical research, 51 11
Meng Zhou, Chenjie Zeng, Yongbo Song, J. Padelford, Gangli Wang, M. Sfeir, Tatsuya Higaki, Rongchao Jin (2017)
On the Non-Metallicity of 2.2 nm Au246 (SR)80 Nanoclusters.Angewandte Chemie, 56 51
Chenjie Zeng, Yuxiang Chen, K. Kirschbaum, K. Appavoo, M. Sfeir, Rongchao Jin (2015)
Structural patterns at all scales in a nonmetallic chiral Au133(SR)52 nanoparticleScience Advances, 1
H. Häkkinen, S. Abbet, Antonio Sánchez, U. Heiz, U. Landman (2003)
Structural, electronic, and impurity-doping effects in nanoscale chemistry: supported gold nanoclusters.Angewandte Chemie, 42 11
Shinjiro Takano, H. Hirai, Satoru Muramatsu, T. Tsukuda (2018)
Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au8)2+ Superatom to a Hydride-Doped (HPd@Au10)3+ Superatom.Journal of the American Chemical Society, 140 39
Lilian Huang, Peng-Cheng Chen, Mohan Liu, Xianbiao Fu, Pavlo Gordiichuk, Yanan Yu, C. Wolverton, Yijin Kang, C. Mirkin (2018)
Catalyst design by scanning probe block copolymer lithographyProceedings of the National Academy of Sciences, 115
Sakiat Hossain, Yoshiki Niihori, L. Nair, B. Kumar, Wataru Kurashige, Y. Negishi (2018)
Alloy Clusters: Precise Synthesis and Mixing Effects.Accounts of chemical research, 51 12
S. Yamazoe, T. Tsukuda (2019)
X-ray Absorption Spectroscopy on Atomically Precise Metal ClustersBulletin of the Chemical Society of Japan
Juanzhu Yan, Sami Malola, Chengyi Hu, Jian Peng, B. Dittrich, B. Teo, H. Häkkinen, Lan-Sun Zheng, N. Zheng (2018)
Co-crystallization of atomically precise metal nanoparticles driven by magic atomic and electronic shellsNature Communications, 9
Jing Liu, K. Krishna, Chanaka Kumara, S. Chattopadhyay, T. Shibata, A. Dass, C. Kumar (2016)
Understanding Au∼98Ag∼46(SR)60 nanoclusters through investigation of their electronic and local structure by X-ray absorption fine structureRSC Advances, 6
Linan Zhou, Dayne Swearer, Hossein Robatjazi, A. Alabastri, P. Christopher, E. Carter, P. Nordlander, N. Halas (2019)
Response to Comment on “Quantifying hot carrier and thermal contributions in plasmonic photocatalysis”Science, 364
Zong‐Jie Guan, Jiu-Lian Zeng, Shang‐Fu Yuan, Feng Hu, Yu-Mei Lin, Quan‐Ming Wang (2018)
Au57 Ag53 (C≡CPh)40 Br12 : A Large Nanocluster with C1 Symmetry.Angewandte Chemie, 57 20
L. Marks, Lingxuan Peng (2016)
Nanoparticle shape, thermodynamics and kineticsJournal of Physics: Condensed Matter, 28
Tyson, Bzowski, Kristof, Kuhn, Sammynaiken, Sham (1992)
Charge redistribution in Au-Ag alloys from a local perspective.Physical review. B, Condensed matter, 45 16
Shuxin Wang, Xiangming Meng, A. Das, Tao Li, Yongbo Song, Tiantian Cao, Xiuyi Zhu, Manzhou Zhu, Rongchao Jin (2014)
A 200-fold quantum yield boost in the photoluminescence of silver-doped Ag(x)Au(25-x) nanoclusters: the 13th silver atom matters.Angewandte Chemie, 53 9
Shuxin Wang, Xiangming Meng, A. Das, Tao Li, Yongbo Song, Tiantian Cao, Xiuyi Zhu, Manzhou Zhu, Rongchao Jin (2014)
A 200‐Fold Quantum Yield Boost in the Photoluminescence of Silver‐Doped AgxAu25‐x Nanoclusters: The 13th Silver Atom Matters.ChemInform, 45
Chenjie Zeng, Yuxiang Chen, K. Kirschbaum, Kelly Lambright, Rongchao Jin (2016)
Emergence of hierarchical structural complexities in nanoparticles and their assemblyScience, 354
C. Femoni, M. Iapalucci, S. Ruggieri, S. Zacchini (2018)
From Mononuclear Complexes to Molecular Nanoparticles: The Buildup of Atomically Precise Heterometallic Rhodium Carbonyl Nanoclusters.Accounts of chemical research, 51 11
Kyuju Kwak, Qing Tang, Minseok Kim, D. Jiang, Dongil Lee (2015)
Interconversion between Superatomic 6-Electron and 8-Electron Configurations of M@Au₂₄(SR)₁₈ Clusters (M = Pd, Pt).Journal of the American Chemical Society, 137 33
Peng-Cheng Chen, Mohan Liu, Jingshan Du, B. Meckes, Shunzhi Wang, Haixin Lin, V. Dravid, C. Wolverton, C. Mirkin (2019)
Interface and heterostructure design in polyelemental nanoparticlesScience, 363
Nan Yan, Nan Xia, Lingwen Liao, Min Zhu, F. Jin, Rongchao Jin, Zhikun Wu (2018)
Unraveling the long-pursued Au144 structure by x-ray crystallographyScience Advances, 4
F. Chang, Shiyao Shan, V. Petkov, Z. Skeete, Aolin Lu, J. Ravid, Jinfang Wu, Jin Luo, Gang Yu, Yang Ren, C. Zhong (2016)
Composition Tunability and (111)-Dominant Facets of Ultrathin Platinum-Gold Alloy Nanowires toward Enhanced Electrocatalysis.Journal of the American Chemical Society, 138 37
Yingwei Li, Tian-Yi Luo, Meng Zhou, Yongbo Song, Nathaniel Rosi, Rongchao Jin (2018)
A Correlated Series of Au/Ag Nanoclusters Revealing the Evolutionary Patterns of Asymmetric Ag Doping.Journal of the American Chemical Society, 140 43
K. Mayer, Jana Weßing, Th. Fässler, Roland Fischer (2018)
Intermetalloide Cluster: Moleküle und Festkörper im DialogAngewandte Chemie
Tatsuya Higaki, Yingwei Li, Shuo Zhao, Qi Li, Site Li, Xiang-Sha Du, Sha Yang, Jinsong Chai, Rongchao Jin (2019)
Atomically Tailored Gold Nanoclusters for Catalytic Application.Angewandte Chemie, 58 25
Shuxin Wang, Shan Jin, Sha Yang, Shuang Chen, Yongbo Song, Jun Zhang, Manzhou Zhu (2015)
Total structure determination of surface doping [Ag46Au24(SR)32](BPh4)2 nanocluster and its structure-related catalytic propertyScience Advances, 1
A. Ghosh, O. Mohammed, O. Bakr (2018)
Atomic-Level Doping of Metal Clusters.Accounts of chemical research, 51 12
J. Padelford, Meng Zhou, Yuxiang Chen, Rongchao Jin, Gangli Wang (2017)
Electronic Transitions in Highly Symmetric Au130 Nanoclusters by Spectroelectrochemistry and Ultrafast SpectroscopyJournal of Physical Chemistry C, 121
Shuxin Wang, Qi Li, Xi Kang, Manzhou Zhu (2018)
Customizing the Structure, Composition, and Properties of Alloy Nanoclusters by Metal Exchange.Accounts of chemical research, 51 11
Indranath Chakraborty, T. Pradeep (2017)
Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles.Chemical reviews, 117 12
S. Nishimura, A. Dao, D. Mott, K. Ebitani, S. Maenosono (2012)
X-ray Absorption Near-Edge Structure and X-ray Photoelectron Spectroscopy Studies of Interfacial Charge Transfer in Gold–Silver–Gold Double-Shell NanoparticlesJournal of Physical Chemistry C, 116
T. Shibata, B. Bunker, Zhenyuan Zhang, D. Meisel, Charles Vardeman, J. Gezelter (2002)
Size-dependent spontaneous alloying of Au-Ag nanoparticles.Journal of the American Chemical Society, 124 40
S. Billinge, I. Levin (2007)
The Problem with Determining Atomic Structure at the NanoscaleScience, 316
M. Bootharaju, Chakra Joshi, Manas Parida, O. Mohammed, O. Bakr (2016)
Templated Atom-Precise Galvanic Synthesis and Structure Elucidation of a [Ag24Au(SR)18](-) Nanocluster.Angewandte Chemie, 55 3
G. Hartland (2011)
Optical studies of dynamics in noble metal nanostructures.Chemical reviews, 111 6
Tatsuya Higaki, Chong Liu, Meng Zhou, Tian-Yi Luo, Nathaniel Rosi, Rongchao Jin (2017)
Tailoring the Structure of 58-Electron Gold Nanoclusters: Au103S2(S-Nap)41 and Its Implications.Journal of the American Chemical Society, 139 29
N. Toshima, T. Yonezawa (1998)
Bimetallic nanoparticles—novel materials for chemical and physical applicationsNew Journal of Chemistry, 22
Sebastian Kenzler, Claudio Schrenk, Andreas Schnepf (2017)
Au108S24(PPh3)16: Bestätigung des allgemeinen Konzeptes metalloider Cluster durch einen hochsymmetrischen nanoskaligen GoldclusterAngewandte Chemie, 129
R. Ferrando, J. Jellinek, R. Johnston (2008)
Nanoalloys: from theory to applications of alloy clusters and nanoparticles.Chemical reviews, 108 3
Kyuju Kwak, Dongil Lee (2018)
Electrochemistry of Atomically Precise Metal Nanoclusters.Accounts of chemical research, 52 1
M. Macdonald, Peng Zhang, Huifeng Qian, Rongchao Jin (2010)
Site-Specific and Size-Dependent Bonding of Compositionally Precise Gold−Thiolate Nanoparticles from X-ray SpectroscopyJournal of Physical Chemistry Letters, 1
Tatsuya Higaki, Chong Liu, Chenjie Zeng, Renxi Jin, Yuxiang Chen, Nathaniel Rosi, Rongchao Jin (2016)
Controlling the Atomic Structure of Au30 Nanoclusters by a Ligand-Based Strategy.Angewandte Chemie, 55 23
Pablo Jadzinsky, G. Calero, C. Ackerson, D. Bushnell, R. Kornberg (2007)
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å ResolutionScience, 318
Yuxiang Chen, Chenjie Zeng, Chong Liu, K. Kirschbaum, C. Gayathri, R. Gil, Nathaniel Rosi, Rongchao Jin (2015)
Crystal Structure of Barrel-Shaped Chiral Au130(p-MBT)50 Nanocluster.Journal of the American Chemical Society, 137 32
Rongchao Jin, Chenjie Zeng, Meng Zhou, Yuxiang Chen (2016)
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities.Chemical reviews, 116 18
Hongjun Zheng, M. Tofanelli, C. Ackerson, K. Knappenberger (2017)
Composition-dependent electronic energy relaxation dynamics of metal domains as revealed by bimetallic Au144-xAgx(SC8H9)60 monolayer-protected clusters.Physical chemistry chemical physics : PCCP, 19 22
A. Kirkland, P. Edwards, D. Jefferson, D. Duff (1990)
Chapter 8. The structure, characterization, and evolution of colloidal metals, 87
The synthesis and structure of atomically precise Au130−xAgx (average x=98) alloy nanoclusters protected by 55 ligands of 4‐tert‐butylbenzenethiolate are reported. This large alloy structure has a decahedral M54 (M=Au/Ag) core. The Au atoms are localized in the truncated Marks decahedron. In the core, a drum of Ag‐rich sites is found, which is enclosed by a Marks decahedral cage of Au‐rich sites. The surface is exclusively Ag−SR; X‐ray absorption fine structure analysis supports the absence of Au−S bonds. The optical absorption spectrum shows a strong peak at 523 nm, seemingly a plasmon peak, but fs spectroscopic analysis indicates its non‐plasmon nature. The non‐metallicity of the Au130−xAgx nanocluster has set up a benchmark to study the transition to metallic state in the size evolution of bimetallic nanoclusters. The localized Au/Ag binary architecture in such a large alloy nanocluster provides atomic‐level insights into the Au−Ag bonds in bimetallic nanoclusters.
Angewandte Chemie International Edition – Wiley
Published: Jul 19, 2020
Keywords: ; ; ; ;
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