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1. The evidence for the metabolic activation of carcinogenic aromatic amines is reviewed. 2. There is a three-step process, N -hydroxylation, esterification and decomposition of the ester to a positively charged electrophile. 3. The difficulties in assessing the nature of the esterification step...
1. N -Hydroxyarylamines, N -hydroxy-N-alkylarylamines, and N,N -dialkyl-arylamine- N -oxides form ferrihaemoglobin in the presence of oxygen; none of the compounds oxidizes ferrohaemoglobin directly. 2. The hydroxylamines produce ferrihaemoglobin in a ‘coupled oxidation’ of the hydroxylamine...
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