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The microwave spectra of five isotopic species of dimethyl sulfide are reported. Changes in rotational constants with isotopic substitution yield the following structural parameters: CS 1.802 A; CSC=98°52′; CH 1.901 A; HCH=109°34′; 2θ=104°22′, where 2θ is the angle between the symmetry...
The absorption and fluorescence spectra of ErCl 3 diluted by LaCl 3 are given with the Zeeman effects of many of the lines. All expected electronic levels to 30 000 cm —1 above the ground state are found, and their interpretation fits into the theoretically expected scheme. Examples are also...
A Taylor series expansion of the intermediate coupling energy levels for Nd 3+ and Er 3+ was calculated. New energy levels can be calculated without rediagonalizing the matrix. A calculation for NdCl 3 is discussed as an example.
Calculations have been made for the 1 s 2 2 s, 1 s 2 3 s, 1 s 2 4 s, 1 s 2 5 s, 2 S ☒ states of Li and Li‐like ions. The functional form used allows for radial correlation in the inner shell and gives sufficient flexibility for describing the outer electron. The energy values obtained for the...
A general scheme is outlined for the calculation of the anisotropy of the polarizability and the depolarization ratio for alkane chains. Computed results are given for these quantities and also for the mean‐square end‐end distance and the mean‐square radius, for chains of up to 10 carbon...
Heat capacities of DyCo 5 are reported for the temperature range extending from 12° to 470°K. Evaluation of the third law entropies of the compound gives in cal deg —1 (g formula weight) —1 55.61±0.05 and 72.05±0.07 at 298.16° and 450°K, respectively. Excess heat capacity is observed...
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