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The mercury photo‐sensitized decomposition of ethane has been carried out with particular emphasis on the high temperature reaction. Evidence is given that under these experimental conditions the ethyl radical becomes unstable around 400°C. An activation energy of 39.5 kcal is assigned to the...
This article describes a proposed new type of adsorption potential associated with surface strain induced in the elimination of unbonded electron orbitals (``first‐order strain''), and strain due to surface (chemical) heterogeneities, or surface impurities (``second‐order strain''). These...
The rates of exchange between N 2 28 and N 2 30 obtained on doubly‐ and singly‐promoted iron catalysts is of the right order to be accounted for by assuming that all nitrogen evaporating from the surface of the catalyst is completely equilibrated with respect to the nitrogen isotope exchange....
The concentration dependence of the conductivities of strong electrolytes is of interest in both theory and application. Older theoretical and empirical equations fail at high concentrations. This article presents three empirical equations for the concentration dependence of conductivity. The...
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