Select All | Select None
Login failed. Please try again.
Forgot your password?
Log in with Facebook
Log in with Google
You can now keep track of new articles from Russian Chemical Bulletin on your personalized homepage!
The vibrational spectra of tetravalent metal halides (M = Si, Ge, Sn) and the corresponding dihalocarbene analogs M II Hal 2 , obtained by the authors, and the relevant published data are compared. The spectra of the M II Hal 2 species exhibit inversion of the M-Hal stretching frequencies (ν s...
Kinetics of hydrogen peroxide decomposition in the presence of the tetraaquapalladium(II) complex in an aqueous solution at 40–70 °C was studied. The reaction rate is the first order with respect to the concentration of both Pd II and H 2 O 2 and the negative first order with respect to...
Novel fluorine-containing carbofunctional organosilicon monomers were synthesized: 3-pentafluorobenzylideneaminopropylethoxysilane (EtO) 3 Si(CH 2 ) 3 N=CH-C 6 F 5 , N -3-methoxydiethoxysilylpropyltrifluoroacetamide (EtO) 2 (MeO)Si(CH 2 ) 3 NHC(O)CF 3 , and 1,1,5-trihydrooctafluoroamyl N...
Earlier unknown N -trinitroethyl derivatives of acetylhydrazine, 4-amino-1,2,4-triazole, and 2,4,6-triamino-1,3,5-triazine, which are potential components for gas-generating formulations, were synthesized.
Site-specific deuterium distribution in molecules of the representative series of natural monoterpenes was studied by quantitative 2 H NMR spectroscopy. “H/D-isotope portraits” of these compounds have general characteristic features reflecting biosynthetic pathways. The data obtained suggest...
A procedure was developed for the synthesis of 1,1′-bishydroperoxydi(C 11 -C 15 -cycloalkyl) peroxides based on homocoupling of geminal 11–15-membered bis(hydroperoxy)cycloalkanes in the presence of BF 3 ⋅OEt 2 .
The reactions of 1,4-dimethoxybenzene with azoles (pyrazole, triazole, and their derivatives, as well as tetrazole) were studied by undivided amperostatic electrolysis at Pt electrodes in MeOH. The process proceeds via the formation of a 1,1,4-trimethoxyarenonium cation as the key intermediate...
The electronic structures and dissociation energies of diazocyclopropane ( 1 ), diazomethane ( 2 ), 2-diazopropane ( 3 ), and diazocyclobutane ( 4 ) were calculated at the density functional B3LYP and the ab initio MP2 levels using the 6-31G(d) basis set and at the G2(MP2,SVP)//B3LYP/6-31G(d)...
Triethoxysilanol was isolated for the first time by hydrolysis of chloro(triethoxy)silane in an organic solvent in the presence of a heterogeneous base and identified as an individual compound. The synthesis of this compound made it possible to study its physicochemical properties and...
Condensation of aromatic (heteroaromatic) aldehydes with 1,3-dicarbonyl compounds under the 1-butyl-3-methylimidazolium tetrafluoroborate ((Bmim)(BF 4 )) ionic liquid-piperidinium acetate catalytic system (0.2 equiv. of each component) in the absence of a solvent affords, depending on the...
results per page
Save this article to read later. You can see your Read Later on your DeepDyve homepage.
To save an article, log in first, or sign up for a DeepDyve account if you don't already have one.
Sign Up Log In
To subscribe to email alerts, please log in first, or sign up for a DeepDyve account if you don't already have one.
Read and print from thousands of top scholarly journals.
Sign up with Facebook
Sign up with Google
Already have an account? Log in
To get new article updates from a journal on your personalized homepage, please log in first, or sign up for a DeepDyve account if you don't already have one.