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The chemical modification initiated by radicals and the grafting of isotactic polypropylene (i-PP) in the solid state are reviewed. The attack of a radical onto the polypropylene mainchain is led by abstraction of a hydrogen atom to a tert -carbon radical. The tert -carbon radical of the...
Synthesis of functional poly(olefin)s using metallocene and late transition metal catalysts resulting in poly(olefin)s having well defined functional groups either randomly distributed along the polymer chain or on chain ends is an emerging area of active interest. Such functional groups...
Miniemulsion polymerization has recently exploded in terms of publications and the development of a wide range of useful polymer materials only accessible through this polymerization technique. In the first part of this article, the fundamental aspects involved in the preparation and...
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