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A general approach is formulated to the design of crystal-forming fullerene-like clusters X n Y n from which zeolite-like covalent crystals based on IV-IV, III-V, and II-VI binary semiconductor compounds with diamond-like sp 3 bonds can be constructed and synthesized by means of copolymerization...
The electric field effects in the EPR spectra of low-spin ( S = 1/2) Ni 3+ tetragonal centers in KTaO 3 single crystals are investigated. It is revealed that the resonance lines are split and the centers are oriented as a result of the interaction of the external field with the electric dipole...
In order to determine the mechanism responsible for the formation of short-range order in dilute FeSi solid solutions, the chemical bonding, atomic displacements near the metalloid, and the enthalpy of silicon dissolution in iron have been studied within density functional theory. It is found...
The photoinduced semiconductor-metal phase transition occurring for a time Δ t < 1 ps in the surface layer of vanadium dioxide is studied theoretically. A nonthermal mechanism of instability development is considered. An equation for the order parameter ξ of the photoinduced semiconductor-metal...
The dependence of the strain-rate sensitivity coefficient of flow stresses S = d lnσ/ d ln on temperature, strain rate, and grain size in nanocrystalline (NC) metals is analyzed quantitatively in terms of the dislocation-kinetics approach taking into account the properties of grain boundaries as...
The geometric parameters and the hyperfine coupling constants for simple free radicals chosen as model fragments of a middle macroradical in a loaded polymer are calculated. The changes revealed in the hyperfine coupling constants for the α, β, γ, and δ protons and the 13 C nuclei due to the...
The electrical conductivity of the semiconducting phase of vanadium dioxide single crystals is studied over a wide range of temperatures. It is shown that the electrical conductivity varies with temperature as log σ ∼ T in the range 340–170 K and as log σ ∼ 1/ T at temperatures below 120...
The electrical conductivity and photoconductivity of films of composites based on electrically neutral poly(vinyl butyral) with additions of Cu(II)/Cr(III) heteropolynuclear complexes introduced in the form of solutions or mechanically ground polycrystalline powders are studied. Photocurrents in...
The response of a two-dimensional electron system with the spin-orbit interaction to a measuring direct-current electric field is investigated for the case in which the system is disturbed from the equilibrium by a microwave alternating magnetic field. Point nonmagnetic impurities are considered...
The possible existence of complexes formed by the C 60 fullerene or its derivatives with transition metals interacting with the carbon cage via η 6 −π type bonding is discussed. The derivatives C 60 R 6 of the C 60 fullerene ( R = −, H, F, Cl, Br, CN) are analyzed using the density...
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