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The three-step synthesis of new magnetic terpyridine-type ligand-protected gold-coated iron oxide nanoparticles (Fe 3 O 4 @Au-L) with an average size of 30 nm has been proposed, and their properties have been investigated.
4,6-Dinitrobenzo( c )isoxazole (4,6-dinitroanthranil) acts as a dienophile and heterodiene in (4 + 2)-cycloaddition reactions, and its behaviour in σ H -complex formation reactions has been examined.
Room-temperature imidazolium ionic liquids (Rmim)(X) (X = Br, BF 4 , NTf 2 ) as a reaction medium change the reaction course of phosphorus(III) acid esters with primary alkyl halides, aryl bromides, and propargyl bromide to afford hydrophosphoryl compounds, products of oxidation of the starting...
New phosphorus-containing derivatives of natural chlorins have been synthesised.
A phosphorus-containing fullerene derivative was successfully applied as an electron acceptor material in organic solar cells with power conversion efficiencies comparable to the values obtained using the state-of-the-art P3HT/PCBM composite system.
P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of ( E )-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee . The catalytic performance is affected greatly by temperature, CO 2 pressures and structure of catalysts.
A possible mechanism of oxygen atom transfer from enantiopure oxaziridines 1 and 2 to 2-phenyl-1,3-dithiane is described.
Studies of N,N -pentamethylene- and N,N -oxydiethylene- N’,N’ -pentamethylenethiocarbamoylsulfenamide zinc(II) complexes by UV and NMR spectroscopy and X-ray diffraction showed the ligand coordination to the metal in a bidentate–chelate manner through the thionic sulfur atom and sulfenamide...
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