1 - 9 of 9 articles
Admixture of the chelate ligand bmnpa (N,N-bis(2-methylthio)ethyl-N-((6-neopentylamino-2-pyridyl)methyl)amine) with an equimolar amount of Hg(ClO4)2·3H2O in CH3OH/CH2Cl2, followed by recrystallization from CH3CN/Et2O, yielded the Hg(II) perchlorate complex ((bmnpa)Hg(ClO4)2) (1). Addition of an...
Previous studies have shown that CO2 can insert into divalent Sn and Ge bis(silylamides) to give mixtures of silylated isocyanates and bis(silyl)carbodiimides, albeit rather sluggishly. In order to more effectively utilize the divalent metal bis(silylamides) in synthesis, more active and...
The reaction of the(1R,2R)-N,N′-Bis(2-pyridylmethylene)cyclohexane-1,2-diamine (BPID) ligand with 2 equivalents of GeCl2•(dioxane) produced an unexpected germanium salt (1) while the reaction with two equivalents of TeBr4 resulted in a novel doubly-charged Te salt (2). These compounds represent...
Reactions of 1,n-diaminoalkanes (n = 5, 6, 8) with excess boric acid in the absence of added solvent resulted in novel pentaborate derivatives containing N → B dative bonds. These diaminoalkane-pentaborate adducts include analogous zwitterions, B5O6(OH)4NH2(CH2)5NH3 (1) and B5O6(OH)4NH2(CH2)6NH3...
The reaction of As2O3 with specific thiols gave the respective trithiolates, As(SR)3, except with dithioerythritol where the known monomeric, bicyclic complex was obtained. Dithioerythritol did not react with Bi2O3 while with Bi(NO3)3·5H2O gave the monocyclic dithiolate. Bi(III) with...
Two new complexes of Eu(III) and Tb(III) with the new ligand N,N′,N″-(1,3,5-triazine-2,4,6-triyl)tribenza mide (TBZM) and benzoate (BA) have been isolated and crystallographically characterized. (Tb(BA)2(TBZM)(H2O))2(CF3SO3)2·4CH3CN·2H2O, 1, crystallizes in the triclinic P-1 lattice with unit...
The new germylene ((PhMe2Si)2N)2Ge has been prepared and fully characterized, and the oxidative addition of ((PhMe2Si)2N)2Ge and ((Me3Si)2N)2Ge with the well-known germylene trapping reagent benzil (1,2-phenylethane-1,2-dione) has been carried out. The crystal structures of the resulting...
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