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The influence of cobalt chloride concentration, total chloride concentration and sulphate in the electrolyte on cobalt deposition were studied. The current efficiency increased and the overpotential for electrodeposition of cobalt decreased with increasing cobalt chloride concentration. Only...
Surface modification of Zr 0.9 Ti 0.1 Ni 1.1 Co 0.1 Mn 0.5 V 0.2 Cr 0.1 alloy was accomplished by mechanical grinding (MG). The decrepitation of alloy particles gave rise to a new surface. The effect of MG was systematically studied by X-ray diffraction (XRD), scanning electron microscopy (SEM),...
The corrosion inhibition of mild steel by means of newly synthesised triazole phosphonates 3-Vanilidene amino 1,2,4-triazole phosphonate (VATP), 3-Anisalidene amino 1,2,4-triazole phosphonate (AATP) and 3-paranitro benzylidene amino 1,2,4-triazole phosphonate (PBATP) was studied along with cetyl...
This work investigates the influence of electrode preparation on the electrochemical behaviour of carbon-based supercapacitors. Studies were performed using the same activated carbon and polymer polyvynilidene fluoride (PVDF) in the same proportions (10 wt.% PVDF). Only the way in which these...
A good understanding of the fundamental transport phenomena of water and methanol in PSA (Perfluoro Sulfonic Acid) membranes is one of the keys in developing efficient direct methanol fuel cells (DMFCs). Electro-osmosis, being one of the most important water and methanol transport mechanisms in...
The corrosion resistance of mild steel in 1 M H 2 SO 4 solution was evaluated after addition of Sn 2+ and Zn 2+ , N -acetylcystein (ACC) and S -benzylcystein (BzC) as a function of concentration (5–1000 μM) and solution temperature (35–50°C). Eight blends were also investigated. Both...
A novel modified glassy carbon electrode (GCE) with a binuclear copper complex was fabricated using a cyclic voltammetric method in phosphate buffer solution. This modified electrode shows very efficient electrocatalytic activity for anodic oxidation of both dopamine (DA) and ascorbic acid (AA)...
The corrosion and electrochemical behaviour of pure aluminium in alkaline methanol solutions has been investigated. The results of hydrogen collection experiments showed that aluminium has a lower corrosion rate in alkaline methanol solutions compared to water based solutions and that the...
The electrochemical degradation of 4-chlorophenol and its main by-products was investigated in acid medium using binary oxides electrodes of nominal composition Ti/Ru 0.3 Ti 0.7 O 2 and Ti/Ru 0.3 Sn 0.7 O 2 prepared by thermal decomposition through two different routes: inorganic precursors...
The internal pressure variations of different Nickel-metal hydride batteries were studied. The relationship between the deflection of a battery shell and internal pressure can be determined by thin elastic shell theory, and also by experimental methods. A DNY-2 was specially designed to measure...
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