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Interest in copper as a technologically important material needs to be met with greater understanding of the fundamental chemical reactions of copper. In particular, there is still a lack of universal agreement on the oxidation process of bulk copper and thin copper films. In this study, the...
The voltammetric response of per-cathodic activated carbon steel electrode in deaerated 0.50 m NaHCO 3 solution at pH 8.72 and 25 °C at a scan rate of 25 mV s −1 was investigated. The influence of cycling, potential excursion and scanning rate on the anodic behavior was studied. The results...
Characterisation of a direct methanol fuel cell using an anode fabricated by thermal decomposition from Pt–Ru chloro-complex on Ti mesh is described. The polarisation characteristic of the resultant membrane electrode assembly is compared with that of a conventional MEA with an anode,...
NO decomposition in solid electrolyte cells was investigated in the presence of excess O 2 . The results show that NO is decomposed via an electrocatalytic mechanism rather than electrolysis in the range of 1–4 V of applied voltage. The NO is catalytically decomposed to N 2 on the cathode...
Direct cathodic reduction of dyes which contain an azo-goup in the chromophore was successfully used for decolourisation of intensively coloured concentrates from Nanofiltration treatment of textile effluents. Based on laboratory scale experiments, a technical multi-cathode electrolyser was...
The deposition of manganese oxide on a carbon substrate in manganese acetate solution by anodic deposition was investigated. The effects of electrolyte concentration (0.05–1 m) and temperature (0–50 °C) on the characteristics of the oxide prepared were explored. The surface morphology of the...
Open-circuit potential, polarization and electrochemical impedance spectroscopy (EIS) measurements were used to investigate the corrosion behaviour of Ti–6Al–4V alloy in H 2 SO 4 and HCl solutions. The corrosion rate of the alloy was found to increase with increasing acid concentration. The...
A study has been made of the electrochemical etching of 99.99% aluminum foils at a current density of 50 mA cm −2 in AlCl 3 –HCl solutions (1 m Cl − ) at 80 °C. The solutions were made by dissolving metallic aluminum into 1m HCl solution, to give a Cl − concentration of 1 m. The number...
Polybithiophene (PBT) was freshly electrodeposited on platinum (Pt) and steel electrodes using cyclic voltammetry from 2,2′-bithiophene (BT), electrolyte and acetonitrile (AC). The electrolytes used were LiBF 4 , LiClO 4 , LiCF 3 SO 3 , Bu 4 NBF 4 , Bu 4 NClO 4 , or Bu 4 NCF 3 SO 3 . Black to...
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