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Ti—6Al—7Nb and Ti—5Al—2Nb—1Ta alloys were implanted with N + ions with an ion energy of 75 keV at a dose rate of 1 × 10 17 and 1 × 10 18 ions cm −2 . Open circuit potential (OCP) and potentiodynamic cyclic polarization measurements were carried out on the titanium alloys in Hanks...
The electrode reactions of the Np 3+ /Np couple at liquid Cd and Bi electrodes were investigated by cyclic voltammetry at 723, 773 and 823 K in the LiCl–KCl eutectic melt. It was found that the diffusion of Np 3+ in the salt phase was the rate-determining step in the cathodic reaction when the...
Copper anodic layers in solutions of hydroxyethylidenediphosphonic acid (HEDP), phosphoric acid, and phosphoric acid with organic and inorganic additives were analysed in situ using electrochemical impedance spectroscopy (EIS). Salt films formed in HEDP solutions were detected. No salt film was...
Deposition of a thin electroless copper films on PVD copper seed layers in interconnect metallization was investigated for formation of a composite seed layer. Issues such as film stress, adhesion, electrical reliability, and hydrogen incorporation were addressed to determine feasibility of the...
This work deals with the evaluation and characterization of aluminium (99.61%) and some of its alloys namely, Al—Ga—In, Al—Zn, Al—In, Al—Mn and Al—Mg, as anodes in alkaline battery electrolyte. The self-corrosion rate, hydrogen evolution rate and electrochemical properties, such as...
The effect of polyethylene glycol (PEG 1500) as additive and of deposition conditions on Zn—Cr alloy electrodeposition from an acidic sulfate electrolyte at room temperature, without agitation was investigated. PEG polarizes the overall cathodic reaction and inhibits Zn deposition. Cr...
Gel polymer electrolytes were prepared with polyacrylonitrile (PAN) and solutions of a novel quaternary ammonium salt, polysiloxane with quaternary ammonium side groups (PSQAS), in a mixture of ethylene carbonate (EC) and propylene carbonate (PC). The influences of PAN content and salt...
Inductive high-frequency impedance behaviour is often observed in metal electrodeposition systems. This behaviour is typically attributed to equipment limitations or non-idealities in the cell set-up and electrical connections. Such instrumental artefacts would nevertheless be relevant to a...
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