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The initial stages of cobalt–molybdenum electrodeposition on a vitreous carbon electrode were studied to obtain information about the mechanism of cobalt–molybdenum induced codeposition. Solutions containing cobalt sulphate, sodium molybdate and sodium citrate at pH 6.6 were used. A first...
By consecutive deposition at two different current densities from a single sulfate–chloride bath, compositionally modulated multilayered (CMM) coatings of Zn–Ni alloys, with different number, thickness and sequence of the sublayers were obtained. The corrosion resistance of the coatings was...
The corrosion rates of LaNi 5 and LaNi 3.55 Co 0.75 Mn 0.4 Al 0.3 hydride electrodes, soaked in alkaline electrolyte and under charge–discharge cycling, were investigated by linear polarization, Tafel polarization and a new method based on the difference between the charge and discharge...
A galvanic system for the removal of copper from aqueous solutions using a divided flow-through cell is proposed. The present study looks into the feasibility of removing copper from dilute electroplating rinse water and recovering it in metallic form by a galvanic cementation process. This...
Oxidation of toluene to benzaldehyde in the presence of the redox couple V 5+ /V 4+ was carried out in an undivided cell where oxygen gas was continuously bubbled over the cathodic surface and the electrolyte was a mixture of aqueous H 2 SO 4 solution containing V 5+ and toluene. Some...
A novel configuration consisting of one porous alumina plate, two electrodes sputtered on both sides and an organic electrolyte, was developed to analyse in situ vinyl chloride in the gaseous phase. Gold and platinum with several solvents (e.g., 1,4-dioxane aqueous solution, acetonitrile and...
The performance and current distribution of a free-breathing polymer electrolyte membrane fuel cell (PEMFC) was studied experimentally in a climate chamber, in which temperature and relative humidity were controlled. The performance was studied by simulating ambient conditions in the temperature...
The redox behaviour of Mn 3+ /Mn 2+ , Co 3+ /Co 2+ and Ce 4+ /Ce 3+ mediators commonly used in indirect oxidation of organic compounds were evaluated in methane sulfonic acid on a glassy carbon working electrode employing cyclic voltammetry. Manganic methanesulfonate exhibits higher instability...
Cyclic voltammetric and potentiodynamic studies were carried out on 300W carbon steel in Bayer plant solution, at 100 °C, with different alumina concentrations. Alumina behaves as an anodic inhibitor, shifting the critical passivation potentials positively and decreasing the critical passivation...
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