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By anodic oxidation of copper sheets in sulfide anion-containing electrolytes copper chalcogenide semiconductor films suitable for photovoltaic applications can be attained. Anodically chalcopyrite (Cu2S) has been formed as pure, mechanically stable, homogeneous and adhesive polycrystalline...
The numerical simulation of current and temperature distribution in monolithic solid oxide fuel cell (SOFC) stacks requires fast computers because of the large number of mesh points required in casting a complex solid geometry into a finite difference form and the necessity to solve coupled,...
Among the numerous base metals tested for DSA® type electrodes (e.g., titanium and its alloys, zirconium, niobium etc.), tantalum is a potentially excellent substrate owing to its good electrical conductivity and corrosion resistance, and the favourable dielectric properties of its oxide....
The anodic oxidation of potassium bromide to potassium bromate is performed in an undivided cell with hydrogen evolution the major reaction at the counter electrode. The cell used is a dished electrode membrane (DEM) cell. Current density distribution, measured using a segmented electrode, shows...
In measurements of gas hold-up of oxygen and hydrogen as a function of the gas flow rate it was found that the gas hold-up epsiv(ug0) depends on the type of electrolyte and its concentrations as well as on the type of gas. Using an ultrasonic Doppler velocimeter, bubble rise velocities were...
Numerical modelling of charge transfer using the finite element method within the whole active layer of proton exchange membrane fuel cell (PEMFC) electrodes is proposed in order to study the electrocatalyst utilization as characterized by the effectiveness factor. In this way, two modified...
Better performance of and higher electrocatalyst utilization in proton-exchange membrane fuel cells equipped with thin film electrodes is achieved by exploiting pore forming additives in the electrode recipe formulation. Preparing the membrane–electrode assembly by a hot spraying procedure...
The construction of efficient electrolysers requires a detailed knowledge of the mass flows, currents and temperatures in the cell. The paper describes three successive models designed for modelling transfers in an industrial electrolysis cell for fluorine production. The conservation laws for...
A bipolar filter press-type electrically rechargeable Zn/O2 battery has been developed. Reticulated copper foam served as substrate for the zinc deposit on the anodic side, and La0.6Ca0.4CoO3-catalysed bifunctional oxygen electrodes were used on the cathodic side of the cells. The 100cm2 unit...
Water electrolysis from acidified solution was used as a model system to investigate the net contribution of hydrogen bubbles to the pressure drop increase in a three-dimensional electrode. A bed of silvered glass beads in both fixed and fluidized state was used, assuming an unchanging particle...
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