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A novel strategy was developed for tailoring of SiO 2 and TiO 2 nanoparticle surfaces with poly(ε-caprolactone) (PCL). Thus, a self-curable polyester, poly(2-hydroxypropylene maleate) was adsorbed on the nanoparticle surfaces and heated to 180 °C to give a cross-linked polyester layer with...
Several series of symmetrical triblock copolymers were synthesized by the reversible addition fragmentation chain transfer method. They consist of a long block of poly( N -isopropylacrylamide) as hydrophilic, thermoresponsive middle block, which is end-capped by two small strongly hydrophobic...
Silver ions being less toxic than silver nanoparticles, a more safe material can be obtained to be used as antimicrobial coating. This can be achieved by using thiol chemistry and covalently attach the silver nanoparticles in the coating. Our aim is to produce a coating having antimicrobial...
This study describes the radical photopolymerization of acrylate monomers in miniemulsion. Starting from nanosized acrylate droplets (<100 nm) which encapsulate a type I radical photoinitiator (BAPO), UV irradiation led after a few minutes to the formation of polymer nanoparticles of similar...
Colloidal crystallization of copolymer-grafted silica containing ferrocenyl groups in organic solvents and effects of ferrocenyl groups on effective refractive index of colloidal crystal systems were investigated. Poly(ferrocenyl metharylate (FeMA)- co -methyl methacrylate (MMA)-grafted silica...
We report on the fabrication of colloidal clusters through the combination of spherical particles. Polystyrene latex particles bearing amino groups on their surface were used as building blocks of the clusters. Packing of these particles with diameters of 91 and 154 nm into assemblies with...
We present a systematic investigation of the crystallization and aggregation behavior of a poly(1,2-butadiene)- block -poly(ethylene oxide) diblock copolymer (PB- b -PEO) in n -heptane. n -Heptane is a poor solvent for PEO and at 70°C the block copolymer self-assembles into spherical micelles...
Poly(L-lactide) networks (PmLA) hydrophilized with different amounts of 2-hydroxyethyl acrylate (HEA) were investigated by dielectric relaxation spectroscopy, thermally stimulated depolarization currents, and differential scanning calorimetry. The incorporation of HEA units in the PmLA network,...
Water in oil microemulsions, consisting of water, AOT and n-decane, have been used as a model system to investigate the influence of the water soluble polymer PEO on the dynamical behavior of the system. Therefore dielectric relaxation spectroscopy and conductivity, extracted from dielectric...
We report here a novel strategy for fabrication of SiO 2 hollow microspheres with urchin-like structure based on templates from directed assembly of block copolymer, poly(2-cinnamoyloxyethyl acrylate)- block- poly(acrylic acid- co -styrene) (PCEA- b -P(AA- co -Sty)). The structures of template...
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