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The interactions between a surface active imidazolium ionic liquid (IL), 1-tetradecyl-3-methylimidazolium bromide (C 14 mimBr) and bovine serum albumin (BSA) were studied. To investigate the structure changes of BSA induced by addition of C 14 mimBr, this system was studied by surface tension,...
Amino acid-based anionic surfactant, N -dodecanoylglutamic acid, after neutralizing by 2, 2′, 2″-nitrilotriethanol forms micellar solution at 25 °C. Addition of cationic cosurfactants hexadecyltrimethylammonium chloride (CTAC), hexadecylpyridinium chloride (CPC), and hexadecylpyridinium...
The interactions of α-cyclodextrin (α-CD) with the nonionic surfactant decanoyl- N -methyl-glucamide (Mega-10) and the zwitterionic surfactant dimethyldodecylammoniopropanesulfonate (DPS) in their mixed system have been studied using interfacial tension, fluorescence, and nuclear magnetic...
The self-assembly of polystyrene-block-poly( l -lysine) (PS-PLLys·HCl) copolymers with different block lengths has been studied in toluene. The obtained spherical micelles exhibit size variations upon addition of acids or bases, as indicated by light and neutron scattering studies. It is shown...
In this paper, well-defined temperature- and pH-sensitive core-shell microgels were synthesized by graft copolymerization in the absence of surfactant and stabilizer. The microgel particles consisted of poly ( N -isopropylacrylamide (NIPAm)) core crosslinked with N , N ′-methylene-bisacrylamide...
Electrically conducting polystyrene (PS)/polyaniline blends have been prepared through a one-step “anilinium-surfactant template”-assisted emulsion polymerization at room temperature. The self-assembled cylindrical An + PDPSA − micelle formed inside the PS matrix can act as a structure...
Phosphonate-functionalized polymer nanoparticles were synthesized by free-radical copolymerization of vinylphosphonic acid (VPA) with styrene or methyl methacrylate (MMA) using the miniemulsion technique. The influence of different parameters such as monomer and surfactant type, amount of...
Adhesion properties of physically crosslinked hydrogels consisting of partially hydrated poly(sodium acrylate) (PSA) and poly(acrylic acid) (PAA) were investigated. The adhesion force and separation energy between the gels in swollen states were measured using a simple tack-evaluation technique...
A novel gel polymer electrolyte (GPE) that contains Li + ions was fabricated. An appropriate amount of ethyl cellulose (EC) was added to 1 M lithium perchlorate in propylene carbonate to prepare the GPE. The ionic conductivity ( σ ) of the GPE depends on the EC content, and the GPE with an EC...
The block copolymer micellization induced by the disproportionation of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was performed using acids with different acid strengths. A poly(4-vinylbenzyloxy-TEMPO)- block -polystyrene diblock copolymer (PVTEMPO- b -PSt) produced micelles in 1,4-dioxane by...
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