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The structure of a series of three molecular weights of diblock copolymers polystyrene/b-isoprene with 11% volume fraction of polystyrene and low polydispersity has been investigated using small angle X-ray scattering (SAXS). In between the disordered and the BCC ordered state a micellar state...
This second part of a systematic study of the properties of crosslinked-oriented gelatin involves the effects of orientation and water content on the glass transition temperature T g and on the melting behavior. The samples were the same as those in the preceding study, and their transition...
Submicron-size composite polymer particles consisting of polydimethylsiloxane/core and polybutadiene/shell were synthesized by seeded emulsion polymerization. The morphologies of composite particles were affected by polybutadiene ratio in the composite particles. Highly grafted polymer by...
Several stable palladium, platinum, silver, and gold colloids were prepared by reducing the corresponding metal precursors in the presence of protective amphiphilic block copolymers. Some palladium and platinum precursors with different hydrophobicities, namely palladium chloride PdCl 2 ,...
Cationic amphiphilic polymers (e.g. polyvinylpyridinium bromides and polyvinylimidazolium bromides) adopt a compact coiled form in aqueous solutions. In the case of former polymers, the resulting hydrophobic microdomains are evidenced only by fluorescence spectroscopy if a molecular rotor (DMAC)...
Mixed gels of starch and bentonite are investigated in the interval 0.056–0.089 of total solids/water ratio and 0-100% starch in the solids. The bentonite was a sodium calcium bentonite with a Na/Ca ratio of 1.76. In water it forms gels consisting of a network of band-type structures. Starch...
The hydration of dodecyltrimethylammonium hydroxide (DTAOH) micelles was determined by viscosity measurements, giving 39.2 ± 7.0 water molecules per micellized dodecyltrimethylammonium ion. This result is lower than the hydration of DTAB micelles, which is about 65. This difference may be due to...
A linear low-density polyethylene was gamma irradiated in presence of carbon dioxide under supercritical conditions. As already reported, this process can be an interesting way to graft carboxylated functions to the polyethylene chains. In this work a detailed analytical investigation of the...
Fourier transform infrared spectra in the wave number range 450-4500 cm -1 of poly (2-hydroxyethyl methacrylate) PHEMA have been studied as functions of water content in the range 38–2.6 wt % and of temperature in the range 300–373 K. The results show changes in the intensities of the...
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