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Chemistry of Heterocyclic Compounds Volume 42 Issue 12

Subject Areas: Organic Chemistry
Publisher: Kluwer Academic Publishers-Consultants Bureau - Springer Journals
ISSN: 0009-3122
SJR: 37

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Journal Article

Edmunds Lukevics

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0277-x
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Journal Article

Metallocanes of group 14 elements. 1. Derivatives of silicon and germanium. (Review)

Selina, A.; Karlov, S.; Zaitseva, G.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0278-9

Results on the synthesis of silocanes and germocanes, eight-membered heterocycles with the general formula D(CH2CH2Z)2MXY are analyzed and classified. The chemical behavior of these compounds and the characteristics of the element-nitrogen transannular bond are studied.
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Journal Article

8-oxyquinolinate and 8-oxyquinaldinate in silicon complex chemistry — a new face of old ligands

Wagler, J.; Gerlach, D.; Roewer, G.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0279-8

In tris(8-oxyquinolinato)phenylsilicon a novel coordination pattern of two 8-oxyquinolinate moieties in hexacoordinate Si complexes was found: cis-(O,O′)-cis-(N,N′). The product of the reaction between 1-chloro-1,2,5-triphenyl-2,5-diazasilolidine and sodium 8-oxyquinolinate...
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General access to a novel class of silyl heterocycles

Degl’Innocenti, A.; Capperucci, A.; Malesci, I.; Acciai, M.; Castagnoli, G.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0280-2

2-Trimethylsilyl-substituted five-membered heterocycles can be accessed through the reaction of bromo(methoxy)methyltrimethylsilane with 1,2-dithiols, 1,2-mercapto alcohols, 1,2-mercapto amines, and 1,2-hydroxy amines, leading to the formation of several 2-silylated...
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Silazanes plus MCl4-substitution vs. rearrangement reactions

Lehnert, C.; Wagler, J.; Kroke, E.; Roewer, G.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0281-1

Novel silicon and tin compounds were synthesized by the reaction of lithium salts of 1,3-di-phenyl-1,1,3,3-tetramethyldisilazane H(DPTMDS) and 1,1,3,3,5,5-hexamethylcyclotrisilazane H3(HMCTS) with SiCl4 and SnCl4, respectively. The reactions with H(DPTMDS) yield the substitution products...
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Structure of N-(1-silatranylmethyl) and N-(trimethoxysilyl-methyl) derivatives of nitrogen-containing heterocycles according to data of NMR, IR, and UV spectroscopy

Voronkov, M.; Larina, L.; Bolgova, Yu.; Trofimova, O.; Chernov, N.; Pestunovich, V.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0282-0

The 1H, 13C, 15N, and 29Si NMR, IR, and UV spectra of N-(1-silatranylmethyl) and N-(trimethoxysilylmethyl) derivatives of nitrogen heterocycles have been studied. The dependence and interrelation of the chemical shifts of 29Si and 15N nuclei of the silatranyl group in the spectra of...
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Synthesis, molecular and crystal structure, and features of the electronic structure of bis(O’i)-chelated bis(2,2-dimethylbenzo-[2H]-4-oxo-1,3-oxazino-3-methyl)difluorosilane

Korlyukov, A.; Lysenko, K.; Antipin, M.; Shipov, A.; Kramarova, E.; Murasheva, T.; Negrebetskii, Vad.; Ovchinnikov, Yu.; Pogozhikh, S.; Yakovlev, I.; Baukov, Yu.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0283-z

A method has been developed for the synthesis of a bis(O→Si)-chelated bis(2,2-dimethylbenzo[2H]-4-oxo-1,3-oxazino-3-methyl)difluorosilane from 2,2-dimethyl-3-trimethylsilylbenzo[2H]-1,3-oxazin-4-one and bis(chloromethyl)dichlorosilane via the intermediate formation of the corresponding unstable...
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Journal Article

[2+3]Cycloaddition reaction of a kinetically stabilized distibene with a nitrile oxide leading to the formation of a unique heterocyclic compound

Sasamori, T.; Mieda, E.; Nagahora, N.; Tokitoh, N.

2006 Chemistry of Heterocyclic Compounds

doi:10.1007/s10593-006-0284-y

The synthesis of a 1-oxa-5-aza-2,3-distibacyclopent-4-ene derivative by the [2+3]cycloaddition reaction of a kinetically stabilized distibene, BbtSb=SbBbt (Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris-(trimethylsilyl)methyl]phenyl), with MesCNO (Mes = mesityl) has been performed.

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