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The metal–ligand complex, (Ru(bpy)2(dppz))2+ (bpy = 2,2′‐bipyridine, dppz = dipyrido(3,2‐a:2′,3′‐c)phenazine) (Ru‐BD), was used as a spectroscopic probe for studying nucleic acid dynamics. The Ru‐BD complex displays a long lifetime of over 100 ns and a molecular light switch...
Protein misfolding and aggregation are involved in a number of the so‐called “conformational” diseases (e.g., transmissible spongiform encephalopathies and Alzheimer disease). The development of rational strategies to interfere with aggregation is a potential therapeutic approach that...
The structure of horseradish peroxidase (HRP) in phosphate buffered saline (PBS)/dimethyl sulfoxide (DMSO) mixed solvents at different compositions is investigated by IR, electronic absorption, and fluorescence spectroscopies. The fluorescence spectra and the amide I spectra of ferric HRP...
Near‐IR spectroscopic methods have been developed to determine the degree of hydration of human skin in vivo. Noncontact reflectance spectroscopic imaging was used to investigate the distribution of skin moisture as a function of location. A human study in a clinical setting has generated...
The tryptophanylemission decay of the mesophilic β‐galactosidase from Aspergillus oryzae free in buffer and entrapped in agarose gel is investigated as a function of temperature and compared to that of the hyperthermophilic enzyme from Sulfolobus solfataricus. Both enzymes are tetrameric...
Resins from several different genera are studied using Fourier transform (FT)‐Raman spectroscopy. Tree resins can be broadly divided into those that contain diterpenoid components and those that contain triterpenoid components. The diterpenoid resins analyzed are from the genera Pinus, Cedrus,...
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