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In the crystal structure of the title compound, C13H12O3S, the dihedral angle between the mean planes of the 4-tolyl and phenyl rings is 52.6 (1)Degrees. There are weak C-HO hydrogen bonds, which generate rings of graph-set motifs R12(4) and R21(9). The supramolecular aggregation is completed by...
The title compound, C38H24N4O4·2C6H6O, is a 1:2 complex of a pyridylethylperylene derivative (EPY) with phenol. The pyridylethyl& groups are attached to the perylene imide skeleton in a trans fashion. The EPY molecule is centrosymmetric. The EPY molecules are stacked along the a...
The title compound, (Ni(C9H9Br2NO4S)(C8H8N2)(H2O))·C2H5OH, was synthesized in a water–ethanol solution. In the structure, the Ni atom is six‐coordinated by three ligands to form the neutral complex, in which the Ni atom has a distorted octahedral coordination geometry. Molecules form dimers...
Ferric sulfate reacts with diethylenetriamine in the presence of acid under hydrothermal conditions to form the title compound, (C4H16N3)Fe(SO4)3.H2O. The six-coordinate ferrate trianion entity exists as a tri-2-sulfate-bridged chain that propagates along the c axis of the monoclinic unit cell....
In the title centrosymmetric compound, (Mn2(C8H3BrO4)2(C12H8N2)4).4H2O, the MnII atom is surrounded by two O atoms from two 4‐bromoisophthalate dianions and four N atoms from two phen (phen is 1,10‐phenanthroline) heterocycles in a distorted octahedral geometry. Two bromoisophthalate...
In the title compound, (Zn(C4H13N3)2)Cl2·H2O, the ZnII atom is coordinated by six N atoms from two diethylenetriamine ligands in a distorted octahedral geometry. The complex cation is the mer isomer.
The title complex, CdHg(NCS)4(C18H15P)2n, contains slightly distorted trigonal bipyramidal CdN4S and tetrahedral HgP2S2. The CdII atom is coordinated by the N atoms of four thiocyanate ions and the S atom of one thiocyanate ion. The HgII atom is coordinated by two triphenylphosphine P atoms and...
A new one‐dimensional coordination polymer, catena‐poly((aqua(nitrato‐κ2O,O′)copper(II))‐μ‐pyrazine‐2‐carboxylato‐ κ3N1,O:N4), (Cu(C5H3N2O2)(NO3)(H2O))n, has been synthesized and characterized. The coordination environment of the copper(II) ion is distorted octahedral,...
The title compound, C18H16N4OS, crystallizes in space group P21/n with two independent molecules in the asymmetric unit. The bond lengths and angles in both molecules are within normal ranges. There are some weak intermolecular hydrogen-bond interactions in the crystal structure, providing...
The title compound, C12H12Cl3NO2, is a purple chromophore with an absorption at 563 nm in acetone solution. The benzenoid ring in the structure exhibits strong quinoid‐like character. In the crystal structure, the molecules pack in alternating layers that are stabilized by close Cl⋯Cl...
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