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The title compound, C17H9N3O, cyrstallizes with two molecules in the asymmetric unit. Both independent molecules have essentially the same geometry. The angles between the planes of the quinoline group and the phenyl ring of the phthalonitrile group in the two molecules are 84.36 (4) and 83.69...
The title compound, C22H20N4O2S, was synthesized by the intermolecular (3 + 2)‐cycloaddition of azomethine ylide, derived from isatin and sarcosine by a decarboxylative route, and 2‐benzylidene‐5,6‐dihydro‐imidazo(2,1‐b)thiazol‐3‐one. In the molecule, the two...
The structure of the title compound, C15H14Cl2N2O2, comprises an essentially flat molecule (dihedral angle of 3.64 (9)° between the two aromatic rings) with an intramolecular hydrogen‐bonding interaction from the amine N—H group to the phenoxy O atom. Molecules are arranged in lamellar...
In the solid state, 2‐(diphenylphosphinoyl)benzoic acid, (C6H4CO2H)P(O)PPh2, forms a hydrogen‐bonded dimer between the phosphoryl O atom and the O—H group of the benzoic acid moiety, while the O atom of the carbonyl group is involved in an intramolecular contact with the P atom. The...
The title complex, Cu(Me2phen)(N3)22, is disposed about an inversion centre; Me2phen is 4,7-dimethyl-1,10-phenanthroline (C14H12N2). The structure features 2-bridging and terminal azide ligands, chelating Me2phen and the Cu atom in a distorted square pyramidal geometry.
The crystal structure of the title compound, K2Cu(C6H2N2O4)2(H2O).6H2O, consists of mononuclear Cu(pzdc)2(H2O)2- complex anions (pzdc is pyrazine-2,3-dicarboxylate), K+ cations and water molecules, held together by means of K-O/OW bonds and an extended OW-HO/OW and OW-HN hydrogen-bond network....
The title compound, C24H22N2O4, is a methyl ester of a 2‐pyridylalanine in which the amine group is protected. The molecule has four essentially planar segments. Apart from a relatively weak N—H⋯O hydrogen bond, molecules are held together in the solid state only by van der Waals...
The title compound, (Cu(CHO2)2(C6H12N2)(H2O))n, forms a polymeric chain, (Cu(HCOO)2(dabco)(H2O))∞ (dabco is 1,4‐diazabicyclo(2.2.2)octane). Both formate ligands are O‐monodentate anions and dabco acts as a bridging ligand, creating a linear polymeric arrangement interconnected by...
In the crystal structure of the title compound, (CuCl2(C10H22N2)), the CuII atom adopts a distorted square‐planar geometry, the basal plane of which is formed by two N atoms from the cyclohexanediamine ligand, with Cu—N distances of 2.052 (7) Å, and two Cl atoms with Cu—Cl distances...
The title compound, C17H9N3O, cyrstallizes with two molecules in the asymmetric unit. Both independent molecules have essentially the same geometry. The angles between the planes of the quinoline group and the phenyl ring of the phthalonitrile group in the two molecules are 84.36 (4) and...
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