Environmental Geology

Zhang, Cheng; Pei, Jianguo; Xie, Yunqiu; Cao, Jianhua; Wang, Lanling

doi: 10.1007/s00254-007-1111-1pmid: N/A

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO2 in tilled land and shrub.

Accornero, Marina; Marini, Luigi

doi: 10.1007/s00254-007-1112-0pmid: N/A

A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics, kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication, the influence of several trace elements on the ΔG f o, ΔG r o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals. Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions higher than 0.003.

Simsek, Celalettin

doi: 10.1007/s00254-007-1113-zpmid: N/A

Koprubasi, located within Manisa Province near the Izmir, is the biggest uranium mine where uranium ores originate from Neogene aged altered sandstone and conglomerate layers. The main objective of this study is to determine the radiation hazard associated with radioactivity levels of uranium ores, and the rocks and sediments around Koprubasi. In this regard, measured activity levels of 226Ra, 232Th and 40K were compared with world averages. The average activity levels of 226 Ra, 232Th and 40K were measured to be 5369.75, 124.78 and 10.0 Bq/kg in uranium ores, 24.32, 52.94 and 623.38 Bq/kg in gneiss, 46.24, 45.13 and 762.26 Bq/kg in sandstone and conglomerate, 73.11, 43.15 and 810.65 Bq/kg in sediments, respectively. All samples have high 226Ra and 40K levels according to world average level. As these sediments are used as construction materials and in agricultural activities within the study area, the radiation hazard are calculated by using dose rate (D), annual effective dose rate (He), radium equivalent activity (Raeq) and radiation hazard index (Iyr). All the samples have Raeq levels that are lower than the world average limit of 370 Bq/kg. On the other hand, D, He and Iyr values are higher than world average values. These results indicate that the uranium ores in the Koprubasi is the most important contributor to the natural radiation level. The radioactivity levels of sediments and rocks make them unsuitable for use as agricultural soil and as construction materials. Moreover, it is determined that shallow groundwater in sediments and deep groundwater in conglomerate rocks and also surface water sources in the Koprubasi have high 226Ra content. According to environmental radioactive baseline, some environmental protection study must be taken in Koprubasi uranium site and the environment.

Yidana, Sandow; Ophori, Duke; Banoeng-Yakubo, Bruce

doi: 10.1007/s00254-007-1114-ypmid: N/A

A steady state groundwater flow simulation model was developed using available well data and general hydrogeological and geological information, for the Afram Plains area, Ghana. The hydrochemistry of groundwater from wells in the area was then evaluated to determine its suitability for irrigation and domestic uses. The assessment of the irrigation quality of groundwater from this area was based on salinity (EC) and sodium adsorption ratios (SAR), residual sodium carbonate (RSC), and permeability indices (PI). The simulation model reveals that groundwater in the Afram Plains area generally flows from the midsections in the neighborhood of Tease and surrounding areas, where significant recharge takes place, to the outer regions and discharges into the Volta Lake in the southern and eastern sections of the area. Flow magnitude and piezometric maps suggest that there is probably of less potential for groundwater extraction for sustainable irrigation in the central regions of the area, when compared to the other discharge areas. This study reveals that more than 70% of the samples analyzed fall within the C2–S1 category, referring to the medium level salinity and low sodium. Medium salinity waters may be used for irrigation on coarse textured soils with good permeability. About 15% of the data fall within the C3–S2 category, referring to water of high salinity and medium sodicity. High salinity, medium sodicity irrigation water cannot be used on fine-grained soils where drainage is restricted. This is because restricted flow is likely to result in the accumulation of salts in the root zones of crops, leading to salinity and soil clogging crisis. About 3% falls within the C3–S3 (high salinity, high sodicity) category. This category requires special soil management including improved drainage, heavy leaching and the use of chemical amendments on the water. Only one point plots within the extreme salinity–sodicity range. Concentrations of fluoride, arsenic and other natural elements in the area generally fall well within the world health standards for domestic water.

Yesilnacar, M.; Cetin, Hasan

doi: 10.1007/s00254-007-1115-xpmid: N/A

Geomorphological features are essential parts of the environment and they represent an important conditioning factor for the development and distribution of certain biological assemblages, as well as for a variety of human activities. However, environmental geomorphology usually receives very limited or no attention at all in the process of environmental impact assessment (EIA). Nevertheless, the site selection process for hazardous wastes in environmental impact studies for individual projects plays an essential role. In order to determine the most suitable site in a region for municipal/hazardous wastes, several criteria are used, including geology, groundwater condition, climate, and land use. The present work describes a methodology taking advantage of environmental geomorphological features, and reducing these criteria in the site selection procedure in land disposal of waste; in addition, a case study is presented to demonstrate the applicability of the proposed methodology. The validity of the adopted site screening method is explained. This methodology comprises the use of a single geomorphological map to locate suitable landfilling sites for hazardous waste, instead of using separate maps for geological features, climatic features (temperature, precipitation, and speed and direction of the prevailing wind), slope and erosion. Furthermore, the present study is compared with a previous study performed in the GAP region, where the use of land resources is crucial for agricultural and water management purposes. The application of the described selection process and the verified method in this region shows that the adopted method and detailed criteria are valid.

Lamelas, M.; Marinoni, O.; Hoppe, A.; Riva, J.

doi: 10.1007/s00254-007-1116-9pmid: N/A

Zaragoza city is located in the central Ebro Basin, in the Iberian Peninsula. The fluvial terraces formed by the Ebro River present a valuable resource of sand and gravel deposits. However, taking advantage of these available resources implies conflicts with other land use interests like urban and industrial development as well as agricultural use, which has also traditionally occupied the alluvial terraces. These deposits represent a substantial groundwater resource that should be preserved for future generations. The development of spatial decision support systems (SDSS) has greatly assisted efforts for solving land-use conflicts. These systems combine the benefits of geographic information systems (GIS) and decision support methodologies and are therefore suitable to manage sustainable development of urban areas. In this contribution, an extraction suitability map taking into consideration a variety of environmental criteria is created with the help of a SDSS. The method used is the analytical hierarchy process which is integrated in ArcGIS. Areas most suitable to sand and gravel extraction are located in the high terraces, and in those terraces covered by pediments where the thickness of resource is relatively high. These areas are far from valuable natural areas, outside areas most vulnerable to groundwater contamination, and beneath soils with poor irrigation characteristics.

Qin, Q.; Zhu, L.; Ghulam, A.; Li, Z.; Nan, P.

doi: 10.1007/s00254-007-1120-0pmid: N/A

In this paper, temporal dynamics of eco-environmental changes in coastal areas of China during 1981–2000 are investigated based on four key surface parameters including normalized difference vegetation index (NDVI), thermal index, moisture index and surface broadband albedo derived from quantitative remote sensing techniques and meteorological data. Firstly, land surface temperature (LST) and land surface broadband albedo are retrieved by the split-window algorithms and high-order polynomial regression method, respectively, using NOAA/AVHRR series images. Then, moisture index and thermal index, indicators of climate and moisture conditions in the study area, are computed from meteorological data and LST using principal component analysis (PCA). Finally, long-term dynamics of these eco-environmental factors and the reasons responsible for these changes are analyzed further. The results show that during the years from 1981 to 2000, the study area experienced a gradual increase in annual NDVI and climate factors and a decrease in surface annual broadband albedo, which indicates that the coastal thermal and moisture conditions and the subsistence conditions of natural vegetation have changed to a considerable extent. According to the results, a warming and wetting tendency over the last two decades is obvious in the China’s coastal zone that are mainly due to land use changes as of growing urbanization, exhaust emissions from industries and transportations and, partly global climate change. Uncontrolled rapid development of the study area may be blamed for these negative changes as a major driving force. The positive feedback mechanisms between albedo, NDVI and climate factors also partly explain these changes. This study suggests that the method integrating biophysical parameters retrieved from remote sensed images and meteorologic data provides a novel and feasible way to monitor large scale eco-environmental changes.

Li, Xiao; Liao, Qiulin; Wang, Sijing; Liu, Jishan; Lee, Souting

doi: 10.1007/s00254-007-1121-zpmid: N/A

Numerous landslides have occurred during the construction of the Three Gorges Reservoir of the Yangtze River. Although the underlying causal factor of these landslides was heavy rainfall, the construction process was the trigger of some of them. We report here a systematic study aimed at reconstructing the geological history of an ancient landslide and, based on our results, an evaluation of the role of the history on current landslide stability. Data from detailed field surveys and the studies on geological dating revealed that the Baiyian landslide was composed of five structural parts of different geological ages, such as a sliding belt, disturbed rocks, ancient colluvium, alluvium of the Yangtze River and slope wash. The succession of ancient climates, terraces and tectonic processes in the study area were examined from 300 ka ago. The evolutionary history of the Baiyian ancient landslide can be divided into five distinct stages: development, occurrence, deposition, collapse and disintegration. Some parts of the ancient landslide are currently prone to instability due to the combination effects of heavy rainfall and construction of the reservoir.

Wen, X.; Wu, Y.; Wu, J.

doi: 10.1007/s00254-007-1122-ypmid: N/A

The Zhangye Basin, located in arid northwest China, is an important agricultural and industrial center. In recent years rapid development has created an increased demand for water, which is increasingly being fulfilled by groundwater abstraction. Detailed knowledge of the geochemical evolution of groundwater and water quality can enhance understanding of the hydrochemical system, promoting sustainable development and effective management of groundwater resources. To this end, a hydrochemical investigation was conducted in the Zhangye Basin. Types of shallow groundwater in the Zhangye Basin were found to be HCO3 −, HCO3 −–SO4 2−, SO4 2−–HCO3 −, SO4 2−–Cl−, Cl−–SO4 2− and Cl− . The deep aquifer groundwater type was found to be HCO 3 − –SO 4 2− throughout the entire area. Ionic ratio and saturation index calculations suggest that silicate rock weathering and evaporation deposition are the main processes that determine the ionic composition in the study area. The suitability of the groundwater for irrigation was assessed based on the US Salinity Laboratory salinity classification and the Wilcox diagram. In the study area, the compositions of the stable isotopes δ18O and δD in groundwater samples were found to range from −4.00 to −9.28‰ and from −34.0 to −65.0‰, respectively. These values indicate that precipitation is the main recharge source for the groundwater system; some local values indicate high levels of evaporation. Tritium analysis was used to estimate the ages of the different groundwaters; the tritium values of the groundwater samples varied from 3.13 to 36.62 TU. The age of the groundwater at depths of less than 30 m is about 5–10 years. The age of the groundwater at depths of 30–50 m is about 10–23 years. The age of the groundwater at depths of 50–100 m is about 12–29 years. For groundwater samples at depths of greater than 100 m, the renewal time is about 40 years.

Wu, Jichun; Shi, Xiaoqing; Xue, Yuqun; Zhang, Yun; Wei, Zixin; Yu, Jun

doi: 10.1007/s00254-007-1123-xpmid: N/A

Land subsidence in China occurs predominantly in 17 provinces (cities) situated in the eastern and middle regions of the country, including Shanghai, Tianjin and Jiangsu, and Hebei provinces. It is primarily caused by groundwater overpumping. One of the areas most severely affected by land subsidence is the Yangtze Delta, most of which consists of Shanghai City, the Su-Xi-Chang area (Suzhou, Wuxi and Changzhou cities) of Jiangsu Province, and the Hang-Jia-Hu area (Hangzhou, Jiaxing and Huzhou cities) of Zhejiang Province. The excessive exploitation of groundwater forms in a large regional cone of depression and, consequently, land subsidence is also regional, currently centered in the Shanghai and Su-Xi-Chang areas. In 2002, the maximum cumulative subsidence of Shanghai, Su-Xi-Chang and Hang-Jia-Hu were 2.63 m, 2.00 and 1.06 m, respectively. The land subsidence area is continuing to expand throughout the Yangtze Delta. To study the characteristics and the pattern of this land subsidence, the government has implemented a monitoring system involving the placement of 37 groups of extensometers (layers marks) and drilling of more than 1000 observation wells. These provide an invaluable historical record of deformation and pore water pressure and facilitate studies on the special features of soil deformation when the groundwater level changes due to pumping. Several measures have been taken in recent years to control the development of the land subsidence in the different areas; these include groundwater injection, prohibition of pumping deep confined groundwater, and an adjustment of the pumping depth and magnitude of the groundwater withdrawn. At present, although the subsidence area is still increasing slowly, the subsidence rate is controlled.