High-resolution electron microscopy for heterogeneous catalysis researchDedicated to the 80th birthday of Prof. Jing Zhu.Zhu, Yong; Xu, Mingquan; Zhou, Wu
doi: 10.1088/1674-1056/27/5/056804pmid: N/A
Heterogeneous catalysts are the most important catalysts in industrial reactions. Nanocatalysts, with size ranging from hundreds of nanometers to the atomic scale, possess activities that are closely connected to their structural characteristics such as particle size, surface morphology, and three-dimensional topography. Recently, the development of advanced analytical transmission electron microscopy (TEM) techniques, especially quantitative high-angle annular dark-field (HAADF) imaging and high-energy resolution spectroscopy analysis in scanning transmission electron microscopy (STEM) at the atomic scale, strengthens the power of (S)TEM in analyzing the structural/chemical information of heterogeneous catalysts. Three-dimensional reconstruction from two-dimensional projected images and the real-time recording of structural evolution during catalytic reactions using in-situ (S)TEM methods further broaden the scope of (S)TEM observation. The atomic-scale structural information obtained from high-resolution (S)TEM has proven to be of significance for better understanding and designing of new catalysts with enhanced performance.
Thermal transport in semiconductor nanostructures, graphene, and related two-dimensional materialsProject supported by the Republic of Moldova through ...Cocemasov, Alexandr I.; Isacova, Calina I.; Nika, Denis L.
doi: 10.1088/1674-1056/27/5/056301pmid: N/A
We review experimental and theoretical results on thermal transport in semiconductor nanostructures (multilayer thin films, core/shell and segmented nanowires), single- and few-layer graphene, hexagonal boron nitride, molybdenum disulfide, and black phosphorus. Different possibilities of phonon engineering for optimization of electrical and heat conductions are discussed. The role of the phonon energy spectra modification on the thermal conductivity in semiconductor nanostructures is revealed. The dependence of thermal conductivity in graphene and related two-dimensional (2D) materials on temperature, flake size, defect concentration, edge roughness, and strain is analyzed.
Stochastic resonance in an under-damped bistable system driven by harmonic mixing signalProject supported by the National Natural Science Foundation o ...Jin, Yan-Fei
doi: 10.1088/1674-1056/27/5/050501pmid: N/A
Stochastic resonance (SR) is studied in an under-damped bistable system driven by the harmonic mixing signal and Gaussian white noise. Using the linear response theory (LRT), the expressions of the spectral amplification at fundamental and higher-order harmonic are obtained. The effects of damping coefficient, noise intensity, signal amplitude, and frequency on spectral amplifications are explored. Meanwhile, the power spectral density (PSD) and signal-to-noise ratio (SNR) are calculated to quantify SR and verify the theoretical results. The SNRs at the first and second harmonics exhibit a minimum first and a maximum later with increasing noise intensity. That is, both of the noise-induced suppression and resonance can be observed by choosing proper system parameters. Especially, when the ratio of the second harmonic amplitude to the fundamental one takes a large value, the SNR at the fundamental harmonic is a monotonic function of noise intensity and the SR phenomenon disappears.
Chaos generation by a hybrid integrated chaotic semiconductor laserProject supported by the International Science and Technology Cooperation Program o ...Zhang, Ming-Jiang; Niu, Ya-Nan; Zhao, Tong; Zhang, Jian-Zhong; Liu, Yi; Xu, Yu-Hang; Meng, Jie; Wang, Yun-Cai; Wang, An-Bang
doi: 10.1088/1674-1056/27/5/050502pmid: N/A
We design a hybrid integrated chaotic semiconductor laser with short-cavity optical feedback. It can be assembled in a commercial butterfly shell with just three micro-lenses. One of them is coated by a transflective film to provide the optical feedback for chaos generation while insuring regular laser transmission. We prove the feasibility of the chaos generation in this compact structure and provide critical external parameters for the fabrication by theoretical simulations. Rather than the usual changeless internal parameters used in previous simulation research, we extract the real parameters of the chip by experiment. Moreover, the maps of the largest Lyapunov exponent with varying bias current and feedback intensity Kap demonstrate the dynamic characteristics under different external-cavity conditions. Each laser chip has its own optimal external cavity length (L) and feedback intensity (Kap) to generate chaos because of the different internal parameters. We have acquired two ranges of optimal parameters (L = 4 mm, and L = 5 mm, ) for two different chips.
Optimization of pick-up coils for weakly damped SQUID gradiometersProject supported by the Key Project of Shanghai Zhangjiang National Innovation Demo ...Yang, Kang; Wang, Jialei; Kong, Xiangyan; Yang, Ruihu; Chen, Hua
doi: 10.1088/1674-1056/27/5/050701pmid: N/A
The performance of a superconducting quantum interference device (SQUID) gradiometer is always determined by its pick-up coil geometry, such as baseline and radius. In this paper, based on the expressions for the coupled flux threading a magnetometer obtained by Wikswo, we studied how the gradiometer performance parameters, including the current dipole sensitivity, spatial resolution and signal-to-noise ratio (SNR), are affected by its pick-up coil via MatLab simulation. Depending on the simulation results, the optimal pick-up coil design region for a certain gradiometer can be obtained. To verify the simulation results, we designed and fabricated several first-order gradiometers based on the weakly damped SQUID with different pick-up coils by applying superconducting connection. The experimental measurements were conducted on a simple current dipole in a magnetically shielding room. The measurement results are well in coincidence with the simulation ones, indicating that the simulation model is useful in specific pick-up coil design.
Using the Hg x Mg(1−x)Te ternary compound as a room temperature photodetector: The electronic structure, charge transport, and response function of th ...Hasan, Ghasemi; Ali, Mokhtari
doi: 10.1088/1674-1056/27/5/053101pmid: N/A
In the present work, firstly, a first-principles study of the structural, electronic, and electron transport properties of the HgxMg1−xTe (HMT) ternary compound is performed using the ABINIT package and the results are compared with Cd0.9Zn0.1Te (CZT) as a current room-temperature photodetector. Next, the response functions of Hg0.6Mg0.4Te and Cd0.9Zn0.1Te under electromagnetic irradiation with 0.05 MeV, 0.2 MeV, 0.661 MeV and 1.33 MeV energies are simulated by using the MCNP code. According to these simulations, the Hg0.6Mg0.4Te ternary compound is suggested as a good semiconductor photodetector for use at room temperature.