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Rhaman, Md Mhahabubur; Fronczek, Frank R.; Powell, Douglas R.; Hossain, Md. Alamgir
doi: 10.1039/c3dt53467gpmid: 24419223
A new macrocycle-based dinuclear nickel chemosensor selectively binds oxalate anions both in solution and the solid state, displaying a remarkable red shift of the fluorescence band with a visible colour change in water at physiological pH in the presence of an external dye.
Sanz, Sergio; Frost, Jamie M.; Lorusso, Giulia; Evangelisti, Marco; Pitak, Mateusz B.; Coles, Simon J.; Nichol, Gary S.; Brechin, Euan K.
doi: 10.1039/c3dt53502apmid: 24477355
The linear [M(CN)2]− (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [MnIII6] single-molecule magnets (SMMs).
Qiao, Bo; Sun, Shiguo; Jiang, Na; Zhang, Si; Peng, Xiaojun
doi: 10.1039/c3dt53541jpmid: 24500515
An aniline–rhodamine-based ratiometric fluorescent probe (RI) was designed and synthesized. RI, the metal coordinating chromophoric ligand, exhibited high selectivity and sensitivity for Pd2+ ions with a detection limit of 73.8 nM. This method of Pd2+ detection had a 10 min response time.
Cavigliasso, G.; Criddle, A.; Kim, H.-S.; Stranger, R.; Yates, B. F.
doi: 10.1039/c3dt53062kpmid: 24509647
Computational investigation of nitrous oxide cleavage by metal–amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N–N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.
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