journal article
LitStream Collection
Cover Picture: Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O→Cvinyl and N→Cvinyl Trifluoromethanesulfonyl Migration Reactions (Angew. Chem. Int. Ed. 48/2013)
Xu, Xiu‐Hua; Taniguchi, Misaki; Wang, Xin; Tokunaga, Etsuko; Ozawa, Tomohiro; Masuda, Hideki; Shibata, Norio
doi: 10.1002/anie.201308947pmid: N/A
Six transformations in one pot allow the stereoselective synthesis of various di‐ and trisubstituted vinyl triflones, and several heteroaryl triflones from gem‐dibromovinyl substrates. In their Communication on page 12628 ff., N. Shibata et al. explore the key steps of this procedure. The cover picture shows a “Japanese‐style painting” by Mami Shibata (a Tama Art University student), named “Kaze” (“breeze” in English). The six transformations in one pot proceed very smoothly, like birds in a breeze.