Epitaxial B2-NiAl layers formed by nanosecond laser irradiation of thin Al/Ni bilayersMyagkov, V. G.;Bykova, L. E.;Bondarenko, G. N.
doi: 10.1134/S1063785006100026pmid: N/A
Abstract The results of experiments on the synthesis of epitaxial B2-NiAl layers by means of nanosecond laser irradiation of sequentially deposited thin nickel and aluminum layers (Al/Ni bilayers) on a MgO(001) substrate surface are presented. Features of the phase formation under the laser action and during the combustion wave initiation are considered. The rapid formation of an epitaxial B2-NiAl layer is explained in terms of a martensitic-like mechanism of the transfer of reacting atoms via a layer of reaction products. It is suggested that this mechanism can compete with diffusion via grain boundaries and dislocation, thus explaining the ultrafast transfer of reacting atoms via a layer of reaction products for various methods of initiation of the solid-state synthesis.
Interface formation between two organic films based on phthalocyanine and perylene derivativesKomolov, S. A.;Lazneva, É. F.
doi: 10.1134/S1063785006100038pmid: N/A
Abstract The process of interface formation between two organic films composed of donor (copper phthalocyanine, CuPc) and acceptor (perylene-3,4,9,10-tetracarboxylic dianhydride, PTCDA) molecules has been studied in situ using the total current spectroscopy technique. It is established that the donor-acceptor interaction between CuPc and PTCDA molecules do not distort the energy structure of the density of electron states. The main π*, σ*1, and σ*2 bands of antibonding (unoccupied) electron states are identified, which are determined both by C-C bonds in the aromatic rings and by additional C-N and C-O bonds. The width of the interface potential barrier is evaluated and its relation to the limiting polarizability of molecules is demonstrated. The interface potential barrier is formed in the course of negative charge transfer between donor (CuPc) and acceptor (PTCDA) molecules.
Measuring the energy spectra of fast ions produced in inverse Z-pinchSorokin, S. A.
doi: 10.1134/S1063785006100063pmid: N/A
Abstract The energy spectra of fast ions produced in the course of electrodynamic acceleration of deuterium plasma in an inverse Z-pinch geometry have been measured. It is established that the radial acceleration and subsequent free expansion of plasma lead to the formation of a flux of ions with a rather broad energy spectrum. In addition to the main group of ions with energies within 2–10 keV, the flux contains fast ions with energies of up to 200 keV and above.
Quantum isotope effect in “hydrogen solution in palladium-hydroxide proton conductor” heterojunctionsBaikov, Yu. M.
doi: 10.1134/S1063785006100105pmid: N/A
Abstract A hydrogen isotope effect in electrode potentials has been observed for the first time at 368 ± 0.5 K in solid hydroxide protonic PdHx|KOH · nH2O (x < 0.02, n = 0.5 and 1) heterojunctions obtained upon electrochemical activation of Pd|KOH · nH2O|M heterostructures, where M = Pd or C (graphite). The chemical composition of the second (M) electrode did not influence the isotope shift of the electrode potential upon the complete replacement of protium by deuterium, which amounted to 105 ± 15 and 120 ± 20 mV for n = 0.5 and 1, respectively. The isotope shift in the electrode potential of the “hydrogen solution in palladium-hydroxide proton conductor” heterojunction implies the presence of quantum effects. The observed isotope shift is correlated with the isotope effects in the zero-point energies of (i) protons involved in the O-H chemical bonds in the structural units of electrolyte and (ii) hydrogen atoms dissolved in palladium.