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Skoulikaris, Charalampos; Zafirakou, Antigoni
doi: 10.1007/s11356-019-04122-4pmid: 30617898
Data availability and the existence of exchange mechanisms are considered crucial issues for the management of water bodies shared among riparian countries. Moreover, common legislative and technical frameworks are assets that foster the management of transboundary waters in an integrated and sustainable manner. The River Basin Management Plans of the European Union’s Water Framework Directive implementation process not only incorporate a cooperative framework, but also include open access internet-based databases that can enhance cooperation and shed light on water-related conflicts among countries that share transboundary waters. The proposed methodological approach in this research is applied in four transboundary river basins, where Greece is the downstream country, and the upstream countries are not all member states of the European Union. The areas of dispute were found in the 2nd Water Convention Report. For each particular case study, data and information from the respective River Basin Management Plans were used to investigate the actual situation. The results demonstrated that significant conflict situations in the past, which involved both water quality and water quantity issues, could be resolved using continuous and reliable datasets included in the management plans. The use of freely available data sources renders the findings of this work useful for the sustainable management of shared waters.
Mahlia, Teuku; Ismail, Norasyiqin; Hossain, Nazia; Silitonga, Arridina; Shamsuddin, Abd
doi: 10.1007/s11356-019-04563-xpmid: 30937750
Due to global warming and increasing price of fossil fuel, scientists all over the world have been trying to find reliable alternative fuels. One of the most potential candidates is renewable energy from biomass. The race for renewable energy from biomass has long begun and focused on to combat the deteriorating condition of the environment. Palm oil has been in the spotlight as an alternative of bioenergy sources to resolve fossil fuel problem due to its environment-friendly nature. This review will look deep into the origins of palm oil and how it is processed, bioproducts from this biomass, and oil palm biomass-based power plant in Malaysia. Palm oil is usually processed from oil palm fruits and other parts of the oil palm plant are candidates for raw material of bioproduct generation. Oil palm biomass can be turned into three subcategories: bioproduct, biofuels, and biopower. Focusing on biofuel, the biodiesel from palm oil will be explored in detail and its implication in Malaysia as one of the biggest producers of oil palm in the world will also be emphasized comprehensively. The paper presents the detail of a schematic flow diagram of a palm oil mill process of transforming oil palm into crude palm oil and it wastes. This paper will also discuss the current oil palm biomass power plants in Malaysia. Palm oil has been proven itself as a potential alternative to reduce negative environmental impact of global warming.
Singh, Yashvir; Sharma, Abhishek; Singla, Amneesh
doi: 10.1007/s11356-019-05000-9pmid: 30968292
Fossil fuel resource is on the draining stage which leads to an increment in the cost of the petroleum products. Nowadays, research is focused on the development of environment-friendly lubricants which are derivatives of renewable sources. Bio-lubricants based on non-edible oil sources are environmentally friendly because they are non-hazardous and biodegradable and no emission of toxic gases were detected when they are used. This study involves the characterizations and advantages, as well as utilization of inedible plant oil–driven bio-lubricants as an alternative for tribological applications. This report also presents the status of the global lubricant market as well as the potential outlook of the bio-lubricants for their future usage. Non-edible plant oil–driven bio-lubricants bear high viscosity, high lubricity, and high viscosity index which can enhance the equipment service life and deserve the ability to carry the high load and results in a minimum amount of metal traces during combustion while applied to engines. Beside their advantages, some of the disadvantages are also there which can be addressed by the employment of certain additives available according to the applications. The detailed study about the different additives utilized during their use in the internal combustion engine is also described in detail during this study. This study provides a detailed description of the possibilities associated with bio-lubricant based on non-edible oil feedstocks to the automotive sector applications.
Sousa, Paloma; Oliveira, André; Silva, Antônio; Lopes, Renata
doi: 10.1007/s11356-019-04989-3pmid: 30972682
Recent studies have shown Cu(0) as a promising material for the removal of organic and inorganic pollutants. However, there is no review addressing the studies performed. This fact may be related to the toxicity of the particles and the copper released in solution that has not motivated researchers, which entails in a reduced number of publications. However, studies point out how to solve the problem of Cu deposition in support materials. In this work, a detailed review of Cu(0) applications was performed. The specific focus was the reaction mechanisms related to adsorption, oxidation, and reduction processes. Initially, the resources that allow the understanding of the reaction mechanism, such as characterization techniques and the experimental conditions for investigation of the species involved in the process, were presented. The studies were evaluated separately, showing the mechanisms involved only with the application of Cu(0) in pure and isolated form and in association with oxidizing or reductive agents, combined with irradiation sources and ultrasonic waves and in the form supported in polymer matrices. It was verified that by the proposed reaction mechanisms, the exclusive participation of Cu(0), being the removal process, explained only by the redox behavior of copper. Therefore, the review showed the need for future research regarding the redox behavior of the contaminants.
Goh, Hui Weng; Lem, Khe Sin; Azizan, Nor Ariza; Chang, Chun Kiat; Talei, Amin; Leow, Cheng Siang; Zakaria, Nor Azazi
doi: 10.1007/s11356-019-05041-0pmid: 30977005
Bioretention systems have been implemented as stormwater best management practices (BMPs) worldwide to treat non-point sources pollution. Due to insufficient research, the design guidelines for bioretention systems in tropical countries are modeled after those of temperate countries. However, climatic factors and stormwater runoff characteristics are the two key factors affecting the capacity of bioretention system. This paper reviews and compares the stormwater runoff characteristics, bioretention components, pollutant removal requirements, and applications of bioretention systems in temperate and tropical countries. Suggestions are given for bioretention components in the tropics, including elimination of mulch layer and submerged zone. More research is required to identify suitable additives for filter media, study tropical shrubs application while avoiding using grass and sedges, explore function of soil faunas, and adopt final discharged pollutants concentration (mg/L) on top of percentage removal (%) in bioretention design guidelines.
Burgess-Conforti, Jason; Moore, Philip; Owens, Phillip; Miller, David; Ashworth, Amanda; Hays, Phillip; Evans-White, Michelle; Anderson, Kelsey
doi: 10.1007/s11356-019-04883-ypmid: 30911970
In 2008, the Mulberry River, a National Wild and Scenic River, was listed as impaired due to low pH (below pH 6.0). Over the last 50 years, the volume of conifers in the Ozark region has increased 115% since 1978 which may result in the acidification of nearby aquatic ecosystems. The objective of this study was to determine if differences exist in soil and litter chemical properties between deciduous and coniferous tree stands. Aboveground litter (n = 200) and soil (n = 400) at 0- to 5- and 5- to 15-cm depths were collected at paired deciduous and coniferous stands at 10 locations within the Mulberry River watershed and analyzed for a suite of chemical parameters. There were no differences (P > 0.05) in several measures of soil acidity between deciduous and coniferous stands. Litter collected from the coniferous stands was more acidic than deciduous litter (4.4 vs 4.7; P < 0.05). Cation exchange capacity, exchangeable Ca and Mg, and water-soluble P and Mg contents differed (P < 0.05) by stand and depth. Cation exchange capacity and exchangeable Ca and Mg were greatest in the 0- to 5-cm depth interval of the coniferous stands. Water-soluble P and Mg contents were greatest within the 0- to 5-cm depth interval which did not differ (P > 0.05) between stand but were greater than the 5- to 15-cm depth interval. Although limited to the top 15-cm of soil, the similarity in soil acidity between stands suggests that conifer growth may not be a substantial source of acidity to the Mulberry River.
Burgess-Conforti, Jason; Moore, Philip; Owens, Phillip; Miller, David; Ashworth, Amanda; Hays, Phillip; Evans-White, Michelle; Anderson, Kelsey
doi: 10.1007/s11356-019-05112-2pmid: 31012073
Fig. 1. was amended to reduce the size of the map and improve formatting of the manuscript. The authors claim this amendment does not affect the information being conveyed.
Luo, Ping; Xiao, Xin; Han, Xiaoxuan; Ma, Yu; Sun, Xiaofei; Jiang, Jiachao; Wang, Hui
doi: 10.1007/s11356-019-04833-8pmid: 30919188
Heavy metal(loid) extraction from soils in overlapped areas of farmland and coal resources (OAFCR) is crucial in understanding heavy metal bioavailability in soil and the subsequent risks to crops and consumers. However, limited attention has been paid to the extraction procedure of heavy metal(loid)s in OAFCR soils in the research. This study therefore explored different single and mixed extraction procedures, such as acetic acid (HOAc), citric acid, ammonium bicarbonate-diethylenetriaminepentaacetic acid (AB-DTPA), ethylene diamine tetraacetic acid + ammonium acetate (EDTA+NH4OAc), and total digestion (HNO3-HClO4-HF) to determine the bioavailability of As, Cd, Cr, Cu, Pb, and Zn in OAFCR soil in Xuzhou, China. The results showed the metal(loid) extraction capacity from soil of the different procedures could be ranked as AB-DTPA > EDTA+NH4OAc > HOAC > citric acid. The transfer ability of heavy metal(loid)s from soil to wheat tissues and from wheat roots to aerial parts was analyzed by calculating the bioconcentration factor and transfer factor, respectively. Transfer factors of all metal(loid)s were < 1 except Cr whose transfer factor from root to shell and straw were > 1. It is suspected that foliar uptake plays a dominant role in Cr uptake. Correlation analysis between the bioavailability of heavy metal(loid)s in soil and uptake in respective wheat tissues was performed to recommend the best extraction procedures for different studies. The results show that AB-DTPA extraction is recommended for Cu uptake to wheat roots, straws, shells and grains, Zn uptake to roots, and Cd uptake to roots and straws.
Périgon, Sophie; Massier, Martin; Germain, Joaquim; Binet, Marie-Noëlle; Legay, Nicolas; Mouhamadou, Bello
doi: 10.1007/s11356-019-04701-5pmid: 30919176
Polychlorinated biphenyls (PCBs) represent a large group of recalcitrant environmental pollutants. Up to now, many studies have focused on bioremediation of PCBs by fungal strains; however, the mechanisms of adaptation of these strains towards PCBs remain unknown despite their importance in developing effective bioremediation processes. We studied five species, each consisting of two strains isolated either from PCB-polluted or PCB-unpolluted substrates (control strains). We investigated their responses to PCB contamination by studying their tolerance to PCBs, their ability to reduce these pollutants, and their expression level of Laccase genes. In Thermothelomyces thermophila, Thermothelomyces heterothallica, Thermoascus crustaceus, and Fusarium solani, all the studied strains showed a similar tolerance and PCB degradation regardless of their origin. In Schizophyllum commune, while both strains showed similar resistance to PCBs, i.e., PCBs and their degradation products presented no toxicity for these strains, the rate of PCB degradation of the strain from a PCB-polluted environment was significantly slightly higher. The PCB degradation did not correlate with the expression level of genes encoding Laccases. These results demonstrate that the tolerance and PCB degradation by the fungal strains, which did not involve Laccase genes, required different adaptation systems which seem to be constitutive or rapidly inducible by PCB according to the fungal species.
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