The Second Law of Thermodynamics: Foundations and StatusSheehan, D.
doi: 10.1007/s10701-007-9164-2pmid: N/A
Over the last 10–15 years the second law of thermodynamics has undergone unprecedented scrutiny, particularly with respect to its universal status. This brief article introduces the proceedings of a recent symposium devoted to this topic, The second law of thermodynamics: Foundations and Status, held at University of San Diego as part of the 87th Annual Meeting of the Pacific Division of the AAAS (June 19–22, 2006). The papers are introduced under three themes: ideal gases, quantum perspectives, and interpretation. Roughly half the papers support traditional interpretations of the second law while the rest challenge it.
Insights into the Second Law of Thermodynamics fromAnisotropic Gas-Surface InteractionsMiller, S.
doi: 10.1007/s10701-007-9167-zpmid: N/A
Thermodynamic implications of anisotropic gas-surface interactions in a closed molecular flow cavity are examined. Anisotropy at the microscopic scale, such as might be caused by reduced-dimensionality surfaces, is shown to lead to reversibility at the macroscopic scale. The possibility of a self-sustaining nonequilibrium stationary state induced by surface anisotropy is demonstrated that simultaneously satisfies flux balance, conservation of momentum, and conservation of energy. Conversely, it is also shown that the second law of thermodynamics prohibits anisotropic gas-surface interactions in “equilibrium”, even for reduced dimensionality surfaces. This is particularly startling because reduced dimensionality surfaces are known to exhibit a plethora of anisotropic properties. That gas-surface interactions would be excluded from these anisotropic properties is completely counterintuitive from a causality perspective. These results provide intriguing insights into the second law of thermodynamics and its relation to gas-surface interaction physics.
Random Fluctuations of Diathermal and Adiabatic PistonsCrosignani, Bruno; Di Porto, Paolo
doi: 10.1007/s10701-007-9165-1pmid: N/A
A comparison between the standard adiabatic piston dynamics and that of a perfectly conducting (diathermal) piston helps to clarify their different behaviors and, in particular, the anomalously large random displacement of the adiabatic piston as compared to the diathermal one. It is shown to be associated with a situation where the presence of a single massive “particle” (the piston), acting as an internal constraint in a many-particle system, plays a somewhat unexpected relevant role. A significant physical insight accounting for the above difference is gained by means of a simple analysis of the phase space available to our system.
Decoherence Induced EquilibrationSchulman, L.
doi: 10.1007/s10701-007-9169-xpmid: N/A
A pair of harmonic oscillators come in contact and then separate. This could be a model of an atom encountering an electromagnetic field. We explore the coherence properties of the resulting state as a function of the sort of initial condition used. A surprising result is that if one imagines a large collection of these objects repeatedly coming in contact and separating, the asymptotic distribution functions are not Boltzmann distributions, but rather exponentials with the same rate of dropoff.
Vacuum Radiation, Entropy, and Molecular ChaosBurns, Jean
doi: 10.1007/s10701-007-9161-5pmid: N/A
Vacuum radiation causes a particle to make a random walk about its dynamical trajectory. In this random walk the root mean square change in spatial coordinate is proportional to t
1/2, and the fractional changes in momentum and energy are proportional to t
−1/2, where t is time. Thus the exchange of energy and momentum between a particle and the vacuum tends to zero over time. At the end of a mean free path the fractional change in momentum of a particle in a gas is very small. However, at the end of the mean free path each particle undergoes an interaction that magnifies the preceding change, and the net result is that the momentum distribution of the particles in a gas is randomized in a few collision times. In this way the random action of vacuum radiation and its subsequent magnification by molecular interaction produces entropy increase. This process justifies the assumption of molecular chaos used in the Boltzmann transport equation.
Entropy, Its Language, and InterpretationLeff, Harvey
doi: 10.1007/s10701-007-9163-3pmid: N/A
The language of entropy is examined for consistency with its mathematics and physics, and for its efficacy as a guide to what entropy means. Do common descriptors such as disorder, missing information, and multiplicity help or hinder understanding? Can the language of entropy be helpful in cases where entropy is not well defined? We argue in favor of the descriptor spreading, which entails space, time, and energy in a fundamental way. This includes spreading of energy spatially during processes and temporal spreading over accessible microstates states in thermodynamic equilibrium. Various examples illustrate the value of the spreading metaphor. To provide further support for this metaphor’s utility, it is shown how a set of reasonable spreading properties can be used to derive the entropy function. A main conclusion is that it is appropriate to view entropy’s symbol S as shorthand for spreading.
Information Loss as a Foundational Principle for the Second Law of ThermodynamicsDuncan, T.; Semura, J.
doi: 10.1007/s10701-007-9159-zpmid: N/A
In a previous paper (Duncan, T.L., Semura, J.S. in Entropy 6:21, 2004) we considered the question, “What underlying property of nature is responsible for the second law?” A simple answer can be stated in terms of information: The fundamental loss of information gives rise to the second law. This line of thinking highlights the existence of two independent but coupled sets of laws: Information dynamics and energy dynamics. The distinction helps shed light on certain foundational questions in statistical mechanics. For example, the confusion surrounding previous “derivations” of the second law from energy dynamics can be resolved by noting that such derivations incorporate one or more assumptions that correspond to the loss of information. In this paper we further develop and explore the perspective in which the second law is fundamentally a law of information dynamics.