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References (5)
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J. Hvoslef, B. Norén, D. Ginsburg, K. Hartiala, S. Veige, E. Diczfalusy (1958)
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On enantiomorph‐polarity estimationActa Crystallographica Section A, 39
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The stereochemistry of organomercury compounds. II. A redetermination of the structure of mercury(II) cyanide by neutron diffractionJournal of Organometallic Chemistry, 18
- Publisher
- Wiley
- Copyright
- Copyright © 2007 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 0108-2701
- eISSN
- 2053-2296
- DOI
- 10.1107/S0108270107023463
- pmid
- 17609555
- Publisher site
- See Article on Publisher Site
Abstract
Cocrystallization of pyrene with Hg(CN)2 gives a new clathrate, namely bis[dicyanidomercury(II)] pyrene solvate, [Hg(CN)2]2·C16H10, with molecules of pyrene embedded in cavities of the slightly deformed structure of the mercuric salt; the weak intermolecular N...Hg interactions present in pure Hg(CN)2 are maintained in the cocrystal. The X‐ray analysis of the resulting compound reveals unusual organic–inorganic interactions. One molecule of Hg(CN)2 lies on a crystallographic mirror plane, while in the other, only the Hg atom is on the mirror plane. The molecule of pyrene is cut by a mirror plane perpendicular to the plane of the molecule.
Journal
Acta Crystallographica Section C Crystal Structure Communications – Wiley
Published: Jul 1, 2007