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A. North, D. Phillips, F. Mathews (1968)
A semi-empirical method of absorption correctionActa Crystallographica Section A, 24
A. Maverick, S. Buckingham, Q. Yao, J. Bradbury, G. Stanley (1986)
Intramolecular coordination of bidentate Lewis bases to a cofacial binuclear copper(II) complexJournal of the American Chemical Society, 108
The title compound, (Cu(CHO2)2(C6H12N2)(H2O))n, forms a polymeric chain, (Cu(HCOO)2(dabco)(H2O))∞ (dabco is 1,4‐diazabicyclo(2.2.2)octane). Both formate ligands are O‐monodentate anions and dabco acts as a bridging ligand, creating a linear polymeric arrangement interconnected by Owater—H⋯Ocarboxy hydrogen bonds. The deformed square‐pyramidal CuII coordination comprises two N and two O atoms as the base, and a water molecule in the apical position. The point symmetry of the CuII polyhedron and the dabco ligand is mm, and the formate anions lie on the mirror planes ¼, y, z and ¾, y, z.
Acta Crystallographica Section E – Wiley
Published: Sep 1, 2003
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