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Thermodynamic interpretation of the capacity factor

Thermodynamic interpretation of the capacity factor The thermodynamic description of the capacity factor (k′), the most widely used retention parameter, is presented. The connection of the thermodynamic adsorption equilibrium constant (K) and the retention parameters are shown. Methods for dead volume determination are described. A general thermodynamic approach of the chromatographic processes is described. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chromatographia Springer Journals

Thermodynamic interpretation of the capacity factor

Chromatographia , Volume 25 (11) – Nov 1, 1988

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References (12)

Publisher
Springer Journals
Copyright
Copyright © 1988 by Friedr. Vieweg & Sohn Verlagschesellschaft mbH
Subject
Chemistry; Analytical Chemistry; Organic Chemistry; Biochemistry, general; Plant Sciences; Pharmacy; Measurement Science, Instrumentation
ISSN
0009-5893
eISSN
1612-1112
DOI
10.1007/BF02259413
Publisher site
See Article on Publisher Site

Abstract

The thermodynamic description of the capacity factor (k′), the most widely used retention parameter, is presented. The connection of the thermodynamic adsorption equilibrium constant (K) and the retention parameters are shown. Methods for dead volume determination are described. A general thermodynamic approach of the chromatographic processes is described.

Journal

ChromatographiaSpringer Journals

Published: Nov 1, 1988

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