Access the full text.
Sign up today, get DeepDyve free for 14 days.
A. Sarac, C. Erbil, A. Soydan (1992)
Polymerization of acrylamide initiated with electrogenerated cerium (IV) in the presence of EDTAJournal of Applied Polymer Science, 44
W. Hsu, J. Kuo, Chuh‐Yung Chen (1993)
Study on aqueous polymerizations of vinyl monomers initiated by metal oxidant–chelating agent redox initiatorsJournal of Polymer Science Part A, 31
C. Erbil, Canan Cin, A. Soydan, A. Sarac (1993)
Polyaminocarboxylic acids–Ce(IV) redox systems as an initiator in acrylamide polymerizationJournal of Applied Polymer Science, 47
L. Eriksson, B. Alm (1993)
Characterization of Activated Sludge and Conditioning with Cationic PolyelectrolytesWater Science and Technology, 28
G. Misra, J. Khatib (1983)
Polymerization of acrylamide initiated by Ce(IV)-lactic acid redox systemColloid and Polymer Science, 261
C. Erbil, A. Soydan, Ayse Aroguz, A. Sarac (1993)
The free-radical polymerization of acrylamide initiated with ceric sulfate in the presence of amino acidsAngewandte Makromolekulare Chemie, 213
G. Shapoval, A. Gorodyskiĭ (1973)
Electrochemical Initiation of PolymerisationRussian Chemical Reviews, 42
F. Mabire, R. Audebert, C. Quivoron (1984)
Synthesis and solution properties of water soluble copolymers based on acrylamide and quaternary ammonium acrylic comonomerPolymer, 25
A. Sarac, Hüseyin Basak, A. Soydan, A. Akar (1992)
Polymerization of acrylamide by electrolytically generated Ce(IV)‐organic acid redox systemsAngewandte Makromolekulare Chemie, 198
A. Akar, Oya Galioǧlu, A. Göçmen, A. Sarac (1990)
Copolymer of ketonic resin-polyacrylonitrileJournal of Applied Polymer Science, 39
K. Behari, U. Agrawal, Rima Das (1993)
Cerium(IV)-sorbose-initiated polymerization of acrylamide and methacrylamidePolymer, 34
Cationic polymerization of N,N,N-trimethyl–N-2-methacryl oxyethyl ammonium chloride (DMAEM-MC) was studied using a new synthesis technique and new initiator system, Sn2+. The Sn2+ was produced by the electrolysis of a sacrificial anode. The polymer was prepared in a batch reactor using only Sn material as electrodes. Factors affecting the conversion and average molecular weight of the polymer by electrolysis were obtained. On the one hand, the results indicated that the agitation rate, initial pH, current density and assembly of electrodes significantly affected both conversion and polymer molecular weight. On the other hand, temperature and monomer concentration were minor factors in the electropolymerization, while these two factors were the major factors in conventional chemical methods. The optimal pHi and agitation rate were 5.50 and 0 rpm, respectively. The reaction rate increased with current density; however, the current efficiency decreased with increase in current density. The results also revealed that the optimum reaction temperature and monomer concentration were 25 ∘C and 0.73 m, respectively.
Journal of Applied Electrochemistry – Springer Journals
Published: Sep 29, 2004
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.